My Mom had her picture taken by Edward Land, a friend of her boss, over 60 years ago.
The entire office was stunned when Mr. Land pulled the film out of the camera, coated it with a noxious chemical, and waited as my mother’s image appeared.
Turned out that she was the first woman to have her portrait taken with a Polaroid Prototype Camera.
I think she still might have that picture...somewhere.
If she does have it, and provenance that it is the first, it would be worth tens of thousands of dollars to a collector.