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Organic LEDs Shine Invisibly
MIT Technology Review ^ | 01/30/2007 | By Prachi Patel-Predd

Posted on 01/31/2007 9:53:42 AM PST by Red Badger

Long-lasting near-infrared LEDs could be used to make cheap, flexible night-vision displays and sensors.

Universal Display Corporation’s phosphorescent organic LED display can be built on a flexible plastic substrate. The company, working with researchers at the University of Southern California and Princeton University, has now made near-infrared emitting LEDs and plans to make a near-infrared version of the flexible display. The display would be invisible to the naked eye but visible through night-vision goggles for covert military operations. Credit: Julie Brown, Universal Display Corporation

Researchers at the University of Southern California have designed a phosphorescent dye molecule that emits near-infrared light and have used it to make long-lasting organic light-emitting diodes (OLEDs).

The diodes could be used to make a cheap and flexible near-infrared (NIR) display that would be unreadable to the naked eye but could be read with night-vision goggles. Such a display could be integrated into a soldier's uniform or a device that could be stashed in a pocket, allowing soldiers to read communications at night without being spotted by enemy snipers.

These organic LEDs could also be converted into the infrared-detector diodes that make night vision possible. Infrared detectors are essentially the reverse of LEDs, converting light into an electric current. Warm objects emit infrared radiation, which has wavelengths longer than near-infrared radiation and is also invisible to the human eye. Just as the light detectors in cameras sense visible light, infrared sensors made of inorganic semiconductors detect infrared light in the night-vision goggles and cameras used by the military, police, border security agents, and firefighters. But detectors based on OLEDs would offer an important benefit: because the thin organic polymers that make up these diodes can be deposited on a variety of substrates, including bendable plastic, organic IR detectors could be flexible enough to incorporate into a helmet visor.

"Flexibility is very beneficial … next-generation displays are all going to be on flexible substrates," says Mark Thompson, a chemistry professor at the University of Southern California, who led the research. Organic LEDs are the crucial technology for flexible displays, because they are easy and cheap to pattern on bendable substrates, he says. They are already being used in camera and cell-phone displays, and they hold tremendous promise for future large-area computer and television screens.

Research in organic LEDs has largely focused on visible-light applications; no one has previously made an organic LED that efficiently emits NIR light. Thompson and his colleagues at Princeton University and Universal Display Corporation, a company based in Ewing, NJ, described their organic LED online in Angewandte Chemie on January 9.

Organic LEDs that emit invisible NIR wavelengths could be used to make displays that you do not want everyone to see. "For covert military applications, night-vision displays will be very important, and these diodes would be key to that," says Ghassan Jabbour, an optical-sciences professor at the University of Arizona in Tucson, who developed the first NIR-emitting organic molecules.

The secret to the new LED is a specially designed phosphorescent dye molecule that the researchers use in the emissive layer sandwiched between the device's two electrodes. Typically, organic LEDs contain an emissive layer that is doped with fluorescent dyes. The electrodes inject negative electrons and positive "holes" into the layer, where the charged particles combine and excite the dye molecules. When the molecules return to their unexcited state, they emit photons. The new phosphorescent molecules emit very efficiently in the NIR region. They also emit light for a longer time than fluorescent dyes, increasing the lifetime of the device--a traditional weak point for organic materials.

The device emits at wavelengths close to 800 nanometers, which is right at the border of the visible and near-infrared spectrum, and boasts an efficiency of more than six percent, which is at least 60 times that of other NIR-emitting devices reported in the past. Right now, it runs for 1,000 hours at its maximum brightness. But at the lower brightness levels required in displays, "we're talking at least a million hours," Thompson says. By comparison, red or green organic LEDs have lifetimes of 100,000 hours, he says.

Gareth Redmond, who studies nanoscale organic photodetectors at the Tyndall National Institute in Cork, Ireland, calls the work a breakthrough toward NIR emission in organic material. Redmond says that the new organic LED shows "really good performance in terms of efficiency and lifetime which hasn't been achieved before."

Thompson and his colleagues plan to make other phosphorescent dye complexes that emit light at wavelengths longer than 800 nanometers, pushing deeper into the IR region. Then, Thompson says, it would be possible to "flip" the organic LED, converting it into an organic IR detector for a night-vision helmet visor. This would require modifying the device structure or tweaking the organic materials, but he says the conversion would be easy because LEDs and photodetectors are "cousins" with essentially the same diode structure but reverse functions--an LED converts electric current into light while a detector does the opposite.

But it is too early to say when such an organic IR detector would be available. It's not just that the jury is still out, he says; "the jury hasn't even been formed."


TOPICS: Business/Economy; Miscellaneous; News/Current Events; Technical
KEYWORDS: electronic; energy; light; military
I want one in my windshield!............
1 posted on 01/31/2007 9:53:44 AM PST by Red Badger
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To: Red Badger
Such a display could be integrated into a soldier's uniform or a device that could be stashed in a pocket, allowing soldiers to read communications at night without being spotted by enemy snipers.

But don't the enemy snipers usually have night vision goggles?

2 posted on 01/31/2007 9:58:03 AM PST by Maceman (This is America. Why must we press "1" for English?)
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To: Red Badger
Ya, but then you'd need one of these to drive...


3 posted on 01/31/2007 9:59:09 AM PST by wizecrakker (Trying to behave)
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To: Maceman
I don't really know, but assume they would. However the display would be more difficult to see because the IR probably doesn't travel as far................just a guess.......
4 posted on 01/31/2007 10:00:51 AM PST by Red Badger (Rachel Carson is responsible for more deaths than Adolf Hitler...............)
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To: wizecrakker

I drive like that now!...............I hate contacts........


5 posted on 01/31/2007 10:01:41 AM PST by Red Badger (Rachel Carson is responsible for more deaths than Adolf Hitler...............)
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To: Red Badger

As a cummuter cyclist, I've found that a whack of drivers drive like that. ::YIKES::


6 posted on 01/31/2007 10:05:14 AM PST by wizecrakker (Trying to behave)
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To: wizecrakker
Ummm that would be COMMUNTER.

I think a CUMmuter is an entirely different animal...

7 posted on 01/31/2007 10:05:59 AM PST by wizecrakker (Trying to behave)
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To: wizecrakker

If you are a "cummuter", I wouldn't want to see you............on the road or otherwise........


8 posted on 01/31/2007 10:07:26 AM PST by Red Badger (Rachel Carson is responsible for more deaths than Adolf Hitler...............)
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To: Red Badger
If you are a "cummuter", I wouldn't want to see you............on the road or otherwise........

I can understand completely.

It might be more hazardous than hitting an oilslick.

9 posted on 01/31/2007 10:10:43 AM PST by wizecrakker (Trying to behave)
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To: wizecrakker

Now you know why they wear those spandex shorts.........


10 posted on 01/31/2007 10:10:58 AM PST by Red Badger (Rachel Carson is responsible for more deaths than Adolf Hitler...............)
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To: wizecrakker
Ummm that would be COMMUNTER

What is a communter?

11 posted on 01/31/2007 10:14:52 AM PST by CharacterCounts (-)
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To: Red Badger
No spandex for me... I ride a Brooks saddle. Cool, hard, slick leather makes the slipperiness of spandex superfluous. John Wayne didn't need spandex... why? Cuz his saddle wasn't made of composites and foam.

Back to the topic at hand though... I wonder when they will develop visible light organic LED's.

Theoretically you could have wallpaper embedded with those things!

12 posted on 01/31/2007 10:18:32 AM PST by wizecrakker (Trying to behave)
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To: CharacterCounts
Yikes!
C-O-M-M-U-T-E-R

I'm not on my own computer right now, and the keyboard feels all f'd up!

13 posted on 01/31/2007 10:20:07 AM PST by wizecrakker (Trying to behave)
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To: wizecrakker

It's being developed even now......The "Holy Grail" of lighting, luminescent walls and ceilings that produce no heat.........


14 posted on 01/31/2007 10:21:04 AM PST by Red Badger (Rachel Carson is responsible for more deaths than Adolf Hitler...............)
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To: Red Badger
. . .allowing soldiers to read communications at night without being spotted by enemy snipers.

Enemy snipers without night vision goggles.

15 posted on 01/31/2007 10:22:15 AM PST by William Terrell (Individuals can exist without government but government can't exist without individuals.)
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To: Red Badger
I drive like that now!...............I hate contacts........

So does this guy


16 posted on 01/31/2007 10:24:00 AM PST by reagan_fanatic (Every time a jihadist dies, an angel gets its wings.)
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To: Red Badger

I want one in my windshield!............

With the ability to type curses at the jerks holding me up in traffic!


17 posted on 01/31/2007 10:27:17 AM PST by TheKidster (you can only trust government to grow, consolidate power and infringe upon your liberties.)
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To: Red Badger
It's being developed even now......The "Holy Grail" of lighting, luminescent walls and ceilings that produce no heat.........

Tré Cool.

Not to mention that overall ambient lighting would come at a pittance of today's energy consumption.

More proof that only capitalism driven innovation can save us from our dependence on dirty inefficient sources.

18 posted on 01/31/2007 10:32:03 AM PST by wizecrakker (Trying to behave)
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To: wizecrakker
you could have wallpaper

My wallpaper is cute young Asian chicks.
I change it daily so it doesn't get boring.

19 posted on 01/31/2007 10:32:57 AM PST by ASA Vet (The WOT should have been over on 9/12/01.)
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To: TheKidster
With the ability to type curses at the jerks holding me up in traffic!

That would work both ways.

20 posted on 01/31/2007 10:34:18 AM PST by wizecrakker (Trying to behave)
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To: wizecrakker

But of course!


21 posted on 01/31/2007 10:36:36 AM PST by TheKidster (you can only trust government to grow, consolidate power and infringe upon your liberties.)
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To: ASA Vet
My wallpaper is cute young Asian chicks.

I change it daily so it doesn't get boring.

That's wise.

Once they get a taste of western mores, they loose their submissive luster.

22 posted on 01/31/2007 10:37:20 AM PST by wizecrakker (Trying to behave)
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To: wizecrakker
C-O-M-M-U-T-E-R

You spelled "Panda" wrong.

23 posted on 01/31/2007 10:41:32 AM PST by Lazamataz (You are not your mind. You are not your emotions. You are not your pain. All you are is love.)
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To: wizecrakker; Chong
Once they get a taste of western mores, they loose their submissive luster

You think they're submissive?
There was a long thread several years ago arguing about that premise.
Seems the 400 pound American women were on one side, and the guys who'd rejected them for an Asian were on the other.

24 posted on 01/31/2007 10:54:10 AM PST by ASA Vet (The WOT should have been over on 9/12/01.)
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To: Lazamataz

25 posted on 01/31/2007 2:24:02 PM PST by Dead Corpse (Anyone who needs to be persuaded to be free, doesn't deserve to be.)
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To: ASA Vet; wizecrakker

Yikes. Oh sure, we loOse our submissive "luster" once we get "poisoned" by you Westerners. I was such a subservient little woman before that... (Gag!)


26 posted on 02/02/2007 6:59:40 AM PST by Chong
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To: Chong
Ehhh... it was a joke.

Chill Chong.

27 posted on 02/02/2007 8:25:57 AM PST by wizecrakker (Trying to behave)
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