Fine but if launch orders went out from either side, how many missles would work as designed versus malfunctioning? Not very many. That's why so many are needed. More systems are needed than targets in order to compensate for system unreliability.
More air dropped nuclear bombs were needed than targets existed because of expected losses due to enemy air defenses. More subs were needed than targets because some subs might be destroyed by enemy action and some subs could be expected to be lost due to missles malfunctioning in the tube resulting in loss of sub (similar to the Kursk)
Using NASA as a metric, the space agency probably does no better than 50/50 at getting a satellite launch off on time. Unlike a minuteman sitting in a remote silo years on end, NASA missiles are of fresh manufacture and are attended to by swarms of engineers and technicians. All this for no better than a coins toss chance of launching on time.
Comparing NASA launches to military EWO launches is apples to oranges. NASA has to worry about space traffic, weather, plume, debris, and having people in the crash zone. Military launches under war conditions (EWO) have none of those restraints.