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Atomic weights of 10 elements on periodic table about to make an historic change
Eureka Alert ^ | 15 Dec 2010 | Leanne Yohemas

Posted on 12/15/2010 5:23:20 PM PST by smokingfrog

click here to read article


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To: BenKenobi
Relative atomic mass is not an intrinsic elemental property.

Relative atomic mass is a synonym for atomic weight and closely related to average atomic mass (but not a synonym for atomic mass), the weighted mean of the atomic masses of all the atoms of a chemical element found in a particular sample, weighted by isotopic abundance.[5] This is frequently used as a synonym for the standard atomic weight and it is correct to do so since the standard atomic weights are relative atomic masses, although it is less specific to do so.

101 posted on 12/15/2010 9:26:41 PM PST by SeeSac
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To: Hoodat

“How did you go about doing it? Did you count the number of molecules?”

Obviously. Isn’t that what you do with a mole?

Acid sample 1, Acid sample 2

Crystal sample 1, Crystal sample 2.

Weigh both crystal samples. Measure volumes of both acid samples.

Add acid 1 to both crystal sample 1 and 2. Measure volumes needed to dissolve crystals.

Repeat with Crystal sample 1 and crystal sample two with acid sample 2.

Solve for the 4 variables and pray you don’t disturb the scale.


102 posted on 12/15/2010 9:33:52 PM PST by BenKenobi (Obama's book of the month, Herman Melville's Killin' Whitey)
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To: BenKenobi
Relative atomic mass is not an intrinsic elemental property. It’s misleading. It assumes experimentally derived information which may or may not be the case with the actual sample. It’s not universally applicable, and there are many applications for which it is not useful at all. This is why periodic tables should state the mass of the most common isotope which is true no matter what sample you use or how you go about doing things.

Atomic mass has been on the periodic tables since Mendeleev made the first one. But then he didn't know about isotopes. The periodic table was reorganize early on with the valence numbers but the atomic mass remains. It's convention.

103 posted on 12/15/2010 9:34:48 PM PST by SeeSac
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To: SeeSac

Wow, you can quote wikipedia.

Amazing expertise.


104 posted on 12/15/2010 9:35:08 PM PST by BenKenobi (Obama's book of the month, Herman Melville's Killin' Whitey)
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To: BenKenobi
Dang you sure are stubborn!

The old definition has the atomic mass of every element as a ratio of C-12. Now, this is no longer the case. Which is exactly the point I was trying to hammer home earlier.

PLEASE show me where in the article that is stated! Here is what the article says ... MORE ACCURATELY. It says nothing about a change in definition. NO IUPAC definitions are being changed. NONE, NADA, ZIP, NIL.

"The new table, outlined in a report released this month, will express atomic weights of 10 elements - hydrogen, lithium, boron, carbon, nitrogen, oxygen, silicon, sulfur, chlorine and thallium - in a new manner that will reflect more accurately how these elements are found in nature."

105 posted on 12/15/2010 9:39:09 PM PST by SeeSac
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To: SeeSac

“Atomic mass has been on the periodic tables since Mendeleev made the first one.”

You’re right. It has been. Periodic tables cited the mass of the most common isotope, and have done so until now.

“But then he didn’t know about isotopes. The periodic table was reorganize early on with the valence numbers but the atomic mass remains. It’s convention.”

The problem is that this change introduces information that has no relevance to the purpose of the Periodic table. Why was Mendeleev able to make predictions? He hit upon the tables and the columns by arranging them according to their physical principles.

Why is it relevant to the chemistry of Chlorine to know that Cl-37 is one quarter as abundant as Cl-35? You see what the fellow above posted, that expressing it as a ratio of C-12 links the whole table together.


106 posted on 12/15/2010 9:39:32 PM PST by BenKenobi (Obama's book of the month, Herman Melville's Killin' Whitey)
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To: BenKenobi
Wow, you can quote wikipedia. Amazing expertise.

Do you agree with it?

107 posted on 12/15/2010 9:41:42 PM PST by SeeSac
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To: SeeSac

Because it changes the whole relationship of atomic mass as a ratio of C-12. That’s the point.

It’s not more accurate. They are fudging the numbers to make them mean something else quite entirely.

Found in nature. Where? In the universe? Or just here on Earth? Or just in some laboratory in North America? Europe? Russia?

What?


108 posted on 12/15/2010 9:42:10 PM PST by BenKenobi (Obama's book of the month, Herman Melville's Killin' Whitey)
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To: BenKenobi
You’re right. It has been. Periodic tables cited the mass of the most common isotope, and have done so until now.

No. They have cited the mass of the common element.

109 posted on 12/15/2010 9:43:01 PM PST by SeeSac
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To: SeeSac

“Do you agree with it?”

That relative atomic mass is quite different than atomic mass and that they do not mean the same thing? Yes.

I’ve kinda been saying that all along. Glad to have you on board.


110 posted on 12/15/2010 9:43:51 PM PST by BenKenobi (Obama's book of the month, Herman Melville's Killin' Whitey)
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To: BenKenobi
You failed to show me where in the article. You will not go google chlorine atomic mass. You ignore my reference. Good night. I hope you don't blow up the chemistry lab class tomorrow.
111 posted on 12/15/2010 9:45:27 PM PST by SeeSac
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To: SeeSac

‘common element’

What on earth do you mean by ‘common element’. Aren’t Elements supposed to be the same no matter where you go?

Hydrogen is Hydrogen, Helium is Helium.


112 posted on 12/15/2010 9:45:44 PM PST by BenKenobi (Obama's book of the month, Herman Melville's Killin' Whitey)
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To: BenKenobi

You totally ducked responding to the highlighted portion that was relevant to the previous post. Thank you.


113 posted on 12/15/2010 9:47:10 PM PST by SeeSac
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To: BenKenobi

Ah, well. Ze times zey change, non?


114 posted on 12/15/2010 9:47:31 PM PST by Erasmus (Personal goal: Have a bigger carbon footprint than Tony Robbins.)
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To: SeeSac

I didn’t ignore your reference. The reference quotes what I said. Atomic masses are expressed as a ratio of C-12.

Relative atomic masses express the ratio of the isotopes as found here on earth. They are not the same thing. They do not mean the same thing. One references an intrinsic property of the element, and one references experimental data which is sometimes right.

We’ve come to agreement on pretty much everything. You like the change, although I’m not sure why. I don’t. I like my periodic table as is.


115 posted on 12/15/2010 9:50:13 PM PST by BenKenobi (Obama's book of the month, Herman Melville's Killin' Whitey)
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To: BenKenobi
What on earth do you mean by ‘common element’. Aren’t Elements supposed to be the same no matter where you go?

No. Elements have different isotopes according the different areas they are found in or as a result of man's intervention. It is called the "PERIODIC TABLE OF THE ELEMENTS" and thus the atomic weight it displays is the weight of the ELEMENT, NOT the isotope.

116 posted on 12/15/2010 9:51:12 PM PST by SeeSac
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To: BenKenobi
I like my periodic table as is.

Which has the ELEMENT atomic mass just as the new tables will have.

117 posted on 12/15/2010 9:52:28 PM PST by SeeSac
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To: BenKenobi
Atomic masses are expressed as a ratio of C-12.

And the atomic masses expressed on the periodic table of ELEMENTS are the atomic masses of the ELEMENTS, not the atomic masses of the isotopes.

118 posted on 12/15/2010 9:54:20 PM PST by SeeSac
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To: SeeSac

Well sure, yours does now. Mine doesn’t. :) Had it for a long time.


119 posted on 12/15/2010 9:54:20 PM PST by BenKenobi
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To: SeeSac

So what atom of Cl has a mass of 35.45 amu?


120 posted on 12/15/2010 9:55:29 PM PST by BenKenobi
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