Skip to comments.Spotting silicon in graphene, it's dope
Posted on 11/27/2012 1:04:16 PM PST by neverdem
Atomic structures for three-fold and four-fold coordinated silicon impurities in monolayer graphene © APS
A combination of scanning transmission electron microscopy and atomic-resolution spectroscopic techniques has allowed US researchers to pick out individual silicon atoms in a doped graphene sheet. The technique reveals that the silicon atoms can exist in a planar hybridised sp2d like form when bonded to four carbon atoms, as well as the anticipated sp3 form when triply coordinated. The experimental observations mesh with simulations of two-dimensional solids and point the way to a method for exploring single impurities in graphene and related materials.
Stephen Pennycook and colleagues at Oak Ridge National Laboratory, Oak Ridge and at Vanderbilt University, Nashville, Tennessee, explain how investigating local structure and bonding characteristics at the atomic scale has become an important endeavour in materials science. Insights into the way in which impurities and dopants affect structure and bonding are critical to developing technological applications for a wide range of semiconductors and other substances, including graphene. They point out that various techniques have been tried and coupled to density functional theory (DFT) to underpin observations with theoretical foundations. Unfortunately, the electron microscopy techniques used so far have not allowed researchers to probe the bonding configurations of individual atomic impurities.
To overcome this problem, the Tennessee team has recruited atomically resolved electron energy-loss spectroscopy and annular dark-ﬁeld (ADF) imaging carried out on a scanning transmission electron microscope. They demonstrated how well their approach worked by investigating one of the most common impurities in graphene formed by high-temperature chemical vapour deposition, silicon. Silicon impurities arise because the element is ubiquitous in the quartz components of the equipment used in CVD. The presence of silicon can affect graphene's properties and, given that the next likely step with microelectronics devices based on graphene will be their integration into silicon circuitry, an understanding of this element's behaviour in the two-dimensional carbon matrix is essential.
The team explains how ADF allows atom-by-atom chemical analysis, but the data reveals a planar image regardless of whether or not the silicon atoms are three or four coordinated. The spectroscopy also offers insights into the nature of the impurities corroborated by DFT calculations. The team suggests that the approach is ideally suited to two-dimensional materials like graphene, but might also be extended to the study of individual molecules in other two-dimensional materials.
Ute Kaiser of the University of Ulm, Germany, is enthusiastic about the potential of the research: It is a very nice work and a further step in the direction of seeing bonds, not just atoms, in materials by using aberration-corrected technology.
W Zhou et al, Phys. Rev. Lett., 2012, 109, 206803 (DOI: 10.1103/PhysRevLett.109.206803)
wow, this could be hugh and series
Being at a point where we can look at individual atoms and see how they fit in a crystal (which implies eventually being able to examine individual atoms in a molecule) is actually pretty cool.
It might be Hugh if it could be translated into english
My son is a doper and will receive his PhD for it in three weeks.
The SNS (Spallation Neutron Source)
has furthered this expertise.
This research is an extension of the
Scanning Electron Microscopy work there
As I type, I'm about 10 Miles away from ORNL
I only hope we are still speaking English in the future when it will be simple science to combine electrons, protons and neutrons to create any element with any properties we desire.
We will then colonize other planets because the ability to download a persons brain to another host body/machine will exist and Earth will fill up.
earth will fill up with tall buildings full of people connected to a virtual world....
Ah yes, but will it have a Spirit/Soul
Will the copy Here be a “Person”
or will The copy There be the “Person”
Pretty cool stuff there, HangnJudge. Just be careful around those ponds or you might wind up glowing in the dark.
No glowing ponds, just the occasional
Two headed Frog and radioactive Deer
I was just in Y-12 last Month
Didn’t get near the Weapons complex though
Bummer, only 80+ y/o Nuns can get there uninvited
The lower silicon in (f) is just a straight substitution for a carbon atom, and is probably a planar structure, but the one in (e) looks like a silicon atom in a silicon crystal (or a carbon atom in diamond, of course) and I would suspect that the silicon and the four carbons around it are a non-planar distortion, at two different levels perpendicular to the image.
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