Nice graphs and info in the comments section https://wattsupwiththat.com/2017/06/30/life-on-earth-was-nearly-doomed-by-too-little-co2/
especially in the first one linking to this https://wattsupwiththat.com/2012/12/07/a-brief-history-of-atmospheric-carbon-dioxide-record-breaking/
Thanks for the note.