Yes. The mediaeval system did use the 7th tone but named it in a round about way.
Note seven of the ut/do (C) hexachord was arrived at in two ways:
1) 4th tone of the fa (F) hexachord (B flat)
2) 3rd tone of the sol (G) hexachord (B natural).
The tone existed, but was named as 4 of 4 (B flat of F) or 3 of 5 (B natural of G).
If I remember correctly, this is from where the flat, natural and sharp signs derive. They are all based on the letter b.