OK, I see what you mean. Yes, that's true. But in the case of CO2 in the atmosphere it's an imbalance because the incoming energy from the sun heats the earth, which radiates infrared. There's more infrared coming from below than above.
"Anyway, I hope I did not become hopelessly technical here."
Don't worry, I do technical.
In that case, CO2 should have an overall negative effect on temperature, by emitting proportionally more IR upwards than it receives from that direction.