While a youth of 10 I was hunting at night with my grandfather for possums (I don’t know why, but it gave me my nickname) and got sprayed directly by a skunk in a tree. You cannot imagine the power of that smell! The dogs also go sprayed; we didn’t see them for days.
If your dog gets sprayed, forget the tomato stuff. Use toothpage to get the smell out. Smear toothpaste over all affected areas, rub it in well, and then wash off. It works great.