There were Lions in Syria and Persia (Iran) in ancient times. DNA has caused many to call into question the out of Africa theory, that is all it is is a theory.
There's the Lion Gate at Mycenae and the story of Heracles (Hercules) and the Nemean lion (Nemea is in the same region of Greece as Mycenae), but I don't know if there is any physical evidence for lions in Greece or the Balkans.