Posted on 03/02/2006 8:15:58 AM PST by aculeus
The hydrogen economy -- with its vision of gas-guzzling engines replaced by hydrogen fuel cells that produce water instead of smog and greenhouse gases -- is a big mistake, according to George Olah, winner of the 1994 Nobel Prize in chemistry.
Olah, whose research in the chemistry of hydrocarbons has led to high-octane fuels and more easily degradable hydrocarbons, is now director of the Loker Hydrocarbon Research Institute at the University of Southern California. He argues that storing energy in the form of methanol, not hydrogen, could end our dependence on fossil fuels and transform carbon dioxide from a global-warming liability into an essential raw material for a methanol-based economy. Olah lays out his plan in a new book, Beyond Oil and Gas: The Methanol Economy, published last week by Wiley-VCH.
Technology Review: Why methanol?
George Olah: Methanol in its own right is an excellent fuel. You can mix it into gasoline -- it's a much better fuel than ethanol. And we have developed a methanol fuel cell.
Methanol is a very simple chemical that can be made in a very efficient way. It is just one oxygen atom inserted into methane, the basal component of natural gas; but methanol is a liquid material which is easily stored, transported, and used.
TR: What's wrong with hydrogen fuel cells?
GO: Even today you could put a pump dispensing methanol at every gasoline station. You can dispense it very well without any [new] infrastructure. For hydrogen, there is no infrastructure. To establish a hydrogen infrastructure is an enormously costly and questionable thing. Hydrogen is a very volatile gas, and there is no way to store or handle it in any significant amount without going to high pressure.
TR: But methanol is a way of storing energy, not a source of energy like gasoline. Where will the energy come from?
GO: The beauty is we can take any source of energy. Whether it's from burning fossil fuels, from atomic plants, from wind, solar, or whatever. What we are saying is it makes a lot better sense, instead of trying to store and transport energy as very volatile hydrogen gas, to convert it into a convenient liquid. And there's a fringe benefit: you really mitigate carbon dioxide in the atmosphere.
TR: How do you make methanol?
GO: One approach is to produce methanol by converting still-existing huge reserves of natural gas, but in entirely different, new ways. Today, methanol is made exclusively from natural gas. Natural gas is incompletely burned, or converted, to synthesis gas, which can then be put together into methanol. Now we have developed ways to completely eliminate the use of synthesis gas.
The second approach involves carbon dioxide. We were co-inventors of the direct methanol fuel cell. This fuel cell uses methanol and produces CO2 and water. It occurred to us that maybe you could reverse the process. And, indeed, you can take carbon dioxide and water, and if you have electric power, you can chemically reduce it into methanol.
So the second leg of our methanol economy approach is to regenerate or recycle carbon dioxide initially from sources where it is present in high concentrations, like flue gases from a power plant burning natural gas. But eventually, and this won't come overnight, we could just take out carbon dioxide from air.
TR: This would help address the problem of carbon dioxide as a greenhouse gas, wouldn't it?
GO: Sequestration [of carbon dioxide] is our [government's] official policy and this is what everybody is swearing by. They say that you stick carbon dioxide down into the earth and at the bottom of the sea, and you solve the problem. [But] how long will it stay down there? Carbon dioxide is a very volatile material. Under the best of conditions it eventually will seep up. Our approach is very different: we simply say that if we need to dispose of carbon dioxide, we need to capture it -- why not use it as a chemical raw material? In other words, recycle it.
TR: We've heard a lot lately about replacing gasoline with ethanol from biological sources and developing better batteries for super-efficient hybrid cars. Do these have a place in a methanol economy?
GO: I think we should explore all possibilities. There is no silver bullet. There is no single solution. I sincerely believe, however, that if you look really impartially, but hard-nosed, at the figures, the needs are so enormous that biological sources per se won't solve them. The president mentioned making ethanol from cellulosic materials. In principle it's possible, but it's a very difficult, undeveloped, and, in my mind, unrealistic technology. Batteries, sure, we should try to find better batteries. But realistically today, fuel cells are a lot more convenient than any battery.
TR: What steps need to be taken now to move toward a methanol economy?
GO: I'm a great believer that technological development is done by major companies. ExxonMobil certainly has some means to do it. The only trouble is that so far they are not coming up with any reasonable solution. Basically, I don't think they like [the methanol economy] very much. If you sit on a large supply of oil and gas, on which you make enormous profits, or if you are an Arab country that has great supplies and great wealth, you wouldn't welcome some crazy guy who comes up and says that mankind can have an ultimate solution which would not be dependent, anymore, on what nature put under your soil.
If this methanol economy makes sense, and I think it does, there is not necessarily a monopoly any more for oil companies. Big chemical companies could equally well do this, or even better. But there is also a need for politicians and the public to say that they want to explore reasonable solutions.
TR: How urgent is the problem?
GO: Man began to use coal on a massive scale during the Industrial Revolution, which was, what, 250 years ago. And we are already, to a very significant degree, depleting what nature gave us. Now, I'm not saying we'll run out of it overnight, but we need to think about how we manage our problems now and how we will manage in the future.
You see natural gas getting in short supply, and we import liquefied natural gas. There are many natural gas sources -- Nigeria, the United Arab Emirates, the North Sea, and so on. The energy content of a single LNG tanker is equivalent to a medium-sized hydrogen bomb. Bad guys are trying to blow up refineries now, and a big tanker is a very inviting target. Who can guarantee that some crazy terrorist won't blow up an LNG tanker? I think a realistic solution is, again, to convert natural gas, as efficiently as we can, into a safe liquid product, like methanol.
All people believe that what they are doing has some importance; but this [methanol research] is, in my mind, the most important thing I ever did in my career, and it has serious implications for society.
methanol is part of the "hydrogen economy" though.
I think we'll see a mixture of a lot of things fueling America in the future. Very diverse in the beginning but finally settling on two or three different things.
check this out....
http://www.netl.doe.gov/publications/proceedings/05/EPSCoR/pdf/wed_am/Tennant.final050610%20EPSCoR.pdf
Eastman built plants in the early 80's to produce syn gas from coal. Methnanol is just a short step away. They have two big plants operating all the time and a third government research plant that might not be still operational. They built the plants so they could eliminate natural gas as feed stock
This article doesn't address the main problem with methanol. In order to produce large quantities of methanol it is necessary to rely on those evil companies who drill wells to produce natural gas. Or we could get those other evil companies who kill trees to double their efforts. No, methanol is evil because of the way it would be produced the same as any petroleum based product.
So instead of volatile hydrogen, you wind up with poisonous methanol, which soaks through the skin and can cause kidney and nervous system damage, including blindess.
"We were co-inventors of the direct methanol fuel cell."
(... and the co-patent holders primed and ready to score massively if we can talk people into using this ! )
bump
That didn't stop the idiots in government from issuing a mandate to reformulate diesel fuel a few years ago. I had to eventually replace every rubber hose and fitting in an older vehicle. I did it myself at a nominal cost. Had I not kept a close watch I could have easily been stranded somewhere by one of these failures. I can't imagine how much it cost others who had to take their vehicles to shops for service.
"Methanol destroys rubber hoses and corrodes metal. It causes reduced fuel mileage and has much less BTUs per gallon. It would cost a fortune to retrofit older vehicles and I doubt it would work in a modern vehicle! The city of Denver tried a tanker of it and within a couple of hours none of the police cars were running."
Bingo! This is the thing that will kill any methanol implementation. Check your owner's manual for any car made after about 1990. It will specifically tell you that using fuel containing methanol will void your warranty.
I think the methanol/ethanol solution is a dead end.
My post number ten should have been directed to you. I wasn't watching where I was going.
Hmmm, I just bet that the process takes a LOT of energy. Ok boys, fire up those nuke plants.
An alcohol is formed by hydroxylating an alkane, which is exactly what ethanol is -- hydroxylated ethane. Remove the -OH radical and it is a simple hydrocarbon, methane's older brother. I'm not sure how you'd go about adding the hydrogen to the ethane molecule, but doing so would render one ethane into two methanes, and it would all still originate with ethanol.
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