tear gas or Pepper balls.
Or just for good old fashioned target marking (like bank dye packs)
(ignore my PM - I derped)
Note also number 1 has a riot shield, number 2 has what looks like a bean bag gun, number 3 has a rifle. So they're ready to escalate from pepper spray balls to bullets in one little stack. This looks like doctrine, but it has serious flaws in the face of armed opposition.