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A demonstration was considered, but decided against:

"It was evident that everyone would suspect trickery. If a bomb were exploded in Japan with previous notice, the Japanese air power was still adequate to give serious interference. An atomic bomb was an intricate device, still in the developmental stage. Its operation would be far from routine. If during the final adjustments of the bomb the Japanese defenders should attack, a faulty move might easily result in some kind of failure. Such an end to an advertised demonstration of power would be much worse that if the attempt had not been made. It was now evident that when the time came for the bombs to be used we should have only one of them available, followed afterwards by others at all-too-long intervals. We could not afford the chance that one of them might be a dud. If the test were made on some neutral territory, it was hard to believe that Japan's determined and fanatical military men would be impressed. If such an open test were made first and failed to bring surrender, the chance would be gone to give the shock of surprise that proved so effective. On the contrary, it would make the Japanese ready to interfere with an atomic attack if they could. Though the possibility of a demonstration that would not destroy human lives was attractive, no one could suggest a way in which it could be made so convincing that it would be likely to stop the war,"

So, the demonstration was at Hiroshima.