My nonscientific 25 years of experience crawling around in various types of fires would indicate that smoke gets into absolutely everything. Despite wearing protective clothing that one might think would stop it, everything stinks after you have been in a house fire including your underwear and your skin. That would indicate that the particles are smaller than one might believe and that dust masks and even N95 type masks are worthless in smoke, that is one of the reasons why we wear Self Contained Breathing Apparatus and not some type of filter mask.
It's the same argument I hear a lot: if I can smell something, then I can be infected by a virus. It assumes I am smelling droplets of something. But that's not correct, I can smell molecules which are 1000 times smaller than any droplet.
even N95 type masks are worthless in smoke
Due to the volatile molecules, not the particles. You will die in a burning house with an N95 mask, no doubt about that. Here's how: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2396464/ Bottom line: various gases can kill you (100 times smaller than the virus) and particles containing acids and other toxins. Some of those particles would be stopped by some masks although the article doesn't go into that.