Yes. At a minimum, they violated the espionage act.
In addition, I believe that there is sufficient evidence to support an indictment on charges of treason- if the matter were ever brought before a Federal Grand Jury.
Unfortunately, ever since Hanoi Jane got a free pass, the Feds seem to think the law is unenforceable. It is still on the books, though:
http://www4.law.cornell.edu/uscode/html/uscode18/usc_sec_18_00002381----000-.html
I'm not talking summary executions here- the minimum penalty is ten years, $10G fine, and being barred from holding public office.