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Presto, Instant Sunglasses!
ScienceNOW ^ | Apr. 24, 2009 | Phil Berardelli

Posted on 04/25/2009 3:15:34 PM PDT by decimon

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For more than a decade, chemical engineer Jiro Abe and colleagues at Aoyama Gakuin University in Japan have been studying the light-sensitive properties of photochromic materials, particularly those derived from a compound called hexaarylbiimidazole (HABI). In its natural state, HABI is colorless, but when ultraviolet light breaks one of the bonds in the molecule, it produces a version that is dark blue. The problem has been that the transformation takes tens of seconds or longer, so the only commercial application has been sunglasses that slowly darken.

When Abe's team began analyzing HABI's chemical structure through simulations and laboratory experiments, they found that by adding naphthalene to the compound, they could accelerate the color change to about 180 milliseconds. Adding a compound called cyclophane instead of naphthalene improved the clear-to-blue conversion even more--to about 30 milliseconds. Better still, Abe and colleagues report in the current issue of the Journal of the American Chemical Society, the cyclophane version of HABI reverts just as rapidly to its colorless state when the UV light source is turned off. And the compound is so stable that the reactions can be repeated thousands of times.

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(Excerpt) Read more at sciencenow.sciencemag.org ...


TOPICS: Computers/Internet; Science
KEYWORDS: habi; photochromics
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Hexaarylbiimidazole. I guess that's six aarylbiimidazoles.
1 posted on 04/25/2009 3:15:34 PM PDT by decimon
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To: decimon

I’ve had Transition lenses for what...a decade now?!


2 posted on 04/25/2009 3:17:24 PM PDT by Southack (Media Bias means that Castro won't be punished for Cuban war crimes against Black Angolans in Africa)
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To: Southack

The breakthrough here is greatly increasing the speed of the transition.


3 posted on 04/25/2009 3:20:40 PM PDT by Moonman62 (The issue of whether cheap labor makes America great should have been settled by the Civil War.)
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To: decimon

I once dated an aarylbiimidazole. She put a hex on me too.


4 posted on 04/25/2009 3:21:36 PM PDT by TheWasteLand
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To: Southack
I’ve had Transition lenses for what...a decade now?!

Do they transit in 30 milliseconds?

5 posted on 04/25/2009 3:21:59 PM PDT by decimon
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To: decimon

Ping me and the other greedy capitalists when commercial production has been successful.


6 posted on 04/25/2009 3:22:30 PM PDT by freespirited (Is this a nation of laws or a nation of Democrats? -- Charles Krauthammer)
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To: decimon

Will they add this to contact lenses in the future? If so, then I won’t bother with LASIK.


7 posted on 04/25/2009 3:23:08 PM PDT by wastedyears (Iron Maiden's gonna get ya, no matter how far!)
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To: decimon

this gets an 8.5 on my “cool-as-heck-o-meter”.


8 posted on 04/25/2009 3:23:42 PM PDT by JohnBrowdie
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To: TheWasteLand
I once dated an aarylbiimidazole. She put a hex on me too.

How quickly did she go from dark blue to clear?

9 posted on 04/25/2009 3:24:43 PM PDT by decimon
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To: decimon
How quickly did she go from dark blue to clear?

Quite some time. She had a lot of engrams.

10 posted on 04/25/2009 3:27:13 PM PDT by TheWasteLand
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To: wastedyears
Will they add this to contact lenses in the future? If so, then I won’t bother with LASIK.

I didn't think of that. It would help people with prescription lenses, wouldn't it.

11 posted on 04/25/2009 3:27:16 PM PDT by decimon
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To: decimon
No mention it this material blocks UV light.

If it doesn’t it is harmful as a sunglasses material.

12 posted on 04/25/2009 3:28:35 PM PDT by Pontiac (Your message here.)
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To: Pontiac
No mention it this material blocks UV light.

True. It reacts to UV light but no mention of blocking it.

13 posted on 04/25/2009 3:35:52 PM PDT by decimon
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To: decimon

Yes, especially those who are finicky about sunglasses, like myself. I just want a pair that are the same size and shape as my regular glasses, but having a small head makes that a bit difficult.


14 posted on 04/25/2009 3:39:50 PM PDT by wastedyears (Iron Maiden's gonna get ya, no matter how far!)
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To: decimon
Do they transit in 30 milliseconds?

I don't walk that fast either, so who cares

15 posted on 04/25/2009 3:39:52 PM PDT by al baby (Hi Mom)
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To: decimon

Whether the material blocks UV doesn’t matter- other UV blockers could be added to lenses that use this.


16 posted on 04/25/2009 3:41:30 PM PDT by Squawk 8888 (TSA and DHS are jobs programs for people who are not smart enough to flip burgers)
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To: Squawk 8888

If you put a UV blocker on it, wouldn’t that stop it from working?


17 posted on 04/25/2009 4:42:00 PM PDT by dfwright (The heart of the wise inclines to the right, but the heart of the fool to the left (Eccl. 10:2, NIV))
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To: decimon
Here's a page that describes anti-nuclear-flash goggles.

Goggles.

18 posted on 04/25/2009 4:54:16 PM PDT by kerosene
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To: kerosene
Here's a page that describes anti-nuclear-flash goggles.

Cool. I wouldn't want to go blind in the three seconds before I became a crispy critter.

19 posted on 04/25/2009 5:06:17 PM PDT by decimon
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To: decimon

Hey, if you’re gonna get fried you might as well see the most beautiful thing in your life a second before...


20 posted on 04/25/2009 5:17:06 PM PDT by ConservativeColumns
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