It doesn't seem likely that Russia would sell him the front line stuff--at least not as a government level policy--because of the repercussions. However, Russia doesn't seem to exercise full control over what comes out of there, so it could happen. From what I've heard, Putin is regaining some semblance of control, but things had gotten pretty loose while his predecessor hit the bottle.
It will be intersting to see just how old these shells are.
I sure hope that stuff never finds its way into the open, but you know someday it will.