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I haven't been bothered by ads or pop-ups at all when using Brave. As far ads within youtube videos, I don't think the browser has much effect upon that. But my overall experience with Brave has been, so far, quite positive. It's not perfect, but has been improving with each update.

I also use Pale Moon -- also quite a fine browser. But I have to constantly fiddle with the ad-on settings( No Script, Ad Block, etc) to get my content to show up properly. Brave handles this this with much less user intervention. If you decide to try it, let me know what you think.