Okay The Day The Earth Stood Still and Forbidden Planet are what I consider classic scifi. Even the original version of The Thing was great
Seriously there can be no such thing as the greatest any movie. How many times have those boring droning drecks, Gone with the Wind and Citizen Kane been lionized? The idea is pure solipsism.
My wife and I watch the original “The Thing” every couple of years. It still creeps us out and I’ve been reviewing it since I first saw it when it was on TV when I was 10. That is one powerful movie. Modern film makers could learn a lot about how worthless modern CGI effects can be without a good story and competent acting.
Freeper 'dead' mentioned Terminator 2: Judgement Day, which truly has everything great sci-fi should, but it's director James Cameron has a twofer here with "Aliens". These films are good examples of the rare sequel surpassing it's original, though many consider "Alien" the better film. Different genres/different tastes.
"Blade Runner" may well be the greatest. The attention to details, cinematography, costumes, practical effects, set designs, daring lighting choices - all in mere service to the writing and excellent actors who drove it home.