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New glass almost as tough as steel [Transparent Aluminum!]
phys.org ^ | 11/04/2015 | Staff

Posted on 11/04/2015 1:21:58 PM PST by Red Badger

Transmittance spectrum of the 54Al2O3-46Ta2O5 glass in the UV/vis region. The inset picture shows the glass sample used for the transmittance experiment. Credit: (c) 2015 Scientific Reports (2015). DOI: 10.1038/srep15233

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(Phys.org)—A team of researchers with The University of Tokyo and Japan Synchrotron Radiation Research Institute has created a type of glass that is stronger than many metals. In their paper published in the journal Scientific Reports, the researchers describe how they overcame one of the major hurdles in creating glass imbued with extra amounts of an oxide of aluminum, by using what they call aerodynamic levitation.

Glass that does not break when dropped or when struck by another object would be useful in a wide variety of applications, from automobile windows, to skyscrapers to smartphones and tablets. For that reason, scientists have been searching for ways to make traditional glass stronger. One of those ways has been to add larger amounts of an oxide of aluminum to the mix, specifically, alumina, because it has one of the highest dissociation energies among oxides. Prior research has shown that glass made with such an addition would be much stronger than traditional glass. Researchers have been prevented from creating such a glass, however, because of a problem in the production process—when more alumina is added to the mix while the glass is being made, silicon dioxide crystals develop where the mix meets the surface that is holding it, making the end product worthless as a glass. In this new effort, the researchers found a way around this problem—by removing the container from the process.

The new process involves causing the mix to be held in the air while it is forming, by pushing it from below with oxygen gas and then using a laser as a spatula to mix the materials together. The end result is a glass with more alumina in it than any other produced to date—a glass that the team reports is transparent, colorless and extremely hard. Testing showed it to be stronger than most metals, and almost as strong as steel.

The only thing holding up the production of shatter-proof smartphone screens using the new glass is that the team still needs to find a way to convert their method to a mass production process—they appear confident that such a way will be found, as they promise to find a way shortly.

Explore further: Apple granted patent for all-glass iPhone, iPad building process

More information: Gustavo A. Rosales-Sosa et al. High Elastic Moduli of a 54Al2O3-46Ta2O5 Glass Fabricated via Containerless Processing, Scientific Reports (2015). DOI: 10.1038/srep15233

Abstract Glasses with high elastic moduli have been in demand for many years because the thickness of such glasses can be reduced while maintaining its strength. Moreover, thinner and lighter glasses are desired for the fabrication of windows in buildings and cars, cover glasses for smart-phones and substrates in Thin-Film Transistor (TFT) displays. In this work, we report a 54Al2O3-46Ta2O5 glass fabricated by aerodynamic levitation which possesses one of the highest elastic moduli and hardness for oxide glasses also displaying excellent optical properties. The glass was colorless and transparent in the visible region, and its refractive index nd was as high as 1.94. The measured Young's modulus and Vickers hardness were 158.3 GPa and 9.1 GPa, respectively, which are comparable to the previously reported highest values for oxide glasses. Analysis made using 27Al Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR) spectroscopy revealed the presence of a significantly large fraction of high-coordinated Al in addition to four-coordinated Al in the glass. The high elastic modulus and hardness are attributed to both the large cationic field strength of Ta5+ ions and the large dissociation energies per unit volume of Al2O3 and Ta2O5.

Journal reference: Scientific Reports


TOPICS: Business/Economy; Japan; Technical
KEYWORDS: aluminumoxide; glass; metallurgy; optics; sapphire; startrek; stthevoyagehome; technology; transparentaluminum
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1 posted on 11/04/2015 1:21:58 PM PST by Red Badger
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To: Red Badger

Way to go, Scottie!


2 posted on 11/04/2015 1:23:08 PM PST by freepertoo
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To: Red Badger

Looks promising. Practical consumer applications?


3 posted on 11/04/2015 1:23:15 PM PST by NY Cajun (I contributed to her pink slip this morning.)
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To: Red Badger; GraceG; SevenofNine
Some Nut back in the 80's in San Francisco claimed a Man from the future gave him the formula.

What ever happened to that?

4 posted on 11/04/2015 1:23:58 PM PST by KC_Lion (The fences are going up all over Europe. We shall not see them down again in our lifetime.)
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To: Red Badger

finally a way to build wonder woman’s jet...


5 posted on 11/04/2015 1:24:05 PM PST by teeman8r (Armageddon won't be pretty, but it's not like it's the end of the world.)
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To: NY Cajun

Cell phones, tablets, glass tables. skyscrapers, doors, windows.


6 posted on 11/04/2015 1:24:17 PM PST by NYRepublican72 (Democrats -- it's always someone else's fault.)
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To: Red Badger

Yes, used by whales for time travel in Star Trek. I remember that.


7 posted on 11/04/2015 1:24:55 PM PST by A CA Guy ( God Bless America, God Bless and keep safe our fighting men and women.)
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To: KC_Lion

He works for Apple, making iPhone screens............................


8 posted on 11/04/2015 1:25:12 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Red Badger

Dangerous stuff.

https://www.youtube.com/watch?v=g7bGw3wnXVs


9 posted on 11/04/2015 1:25:50 PM PST by samtheman (I will build a great, great wall on our southern border... - DT)
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To: NY Cajun

How about screens for tablets that don’t shatter when your kids drop them on the floor?


10 posted on 11/04/2015 1:26:01 PM PST by Hotlanta Mike ('You can avoid reality, but you can�t avoid the consequences of avoiding reality.�)
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To: NY Cajun

Whatever is made of glass and is breakable, now won’t.....................


11 posted on 11/04/2015 1:26:05 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: NY Cajun

I’m hoping for some eyeglasses that won’t scratch, shatter or become diffused...........................


12 posted on 11/04/2015 1:27:13 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: A CA Guy

Where do you keep your nuclear weapons?......................


13 posted on 11/04/2015 1:27:45 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Red Badger

BFL


14 posted on 11/04/2015 1:28:50 PM PST by Lurkina.n.Learnin (It's a shame enobama truly doesn't care about any of this. Our country, our future, he doesn't care)
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To: Red Badger

I invented glass as hard as steel years ago. I just couldn’t solve the one pesky problem of not being able to see through it.

But I am still working on it


15 posted on 11/04/2015 1:30:14 PM PST by Cyman
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To: Red Badger

Aluminum Oxide, industrial Sapphire, has been used on expensive watch lens for decades.

I know Apple looked at them for the latest iPhone but could not get it produced in sufficient quantities fast enough.

http://www.pcmag.com/article2/0,2817,2473339,00.asp


16 posted on 11/04/2015 1:30:27 PM PST by thackney (life is fragile, handle with prayer)
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To: NY Cajun

As I have had to pay $300 to replace the glass on my phone, from accidentally dropping it, I would pay an extra $100 to guarantee that I wouldn’t have to do that on my next phone.

Windshields that never crack from small rocks thrown by vehicles.


17 posted on 11/04/2015 1:30:58 PM PST by Jonty30 (What Islam and secularism have in common is that they are both death cults)
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To: Attention Surplus Disorder; doorgunner69; Steely Tom; jim_trent; LoneRangerMassachusetts

Glass Ping!...........................


18 posted on 11/04/2015 1:31:08 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: NYRepublican72

“Glass that does not break when dropped or when struck by another object would be useful in a wide variety of applications...”

Of course, one would still want glass that breaks for use in, uhm, hmmm.... Oh! Those little glass thingies on the fire alarms!


19 posted on 11/04/2015 1:31:34 PM PST by 21twelve (http://www.freerepublic.com/focus/f-news/2185147/posts It is happening again.)
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To: Red Badger

I am wary of anything with high dissociation energies. I already get tired getting by butt up off a chair.


20 posted on 11/04/2015 1:32:10 PM PST by USMCPOP (Father of LCpl. Karl Linn, KIA 1/26/2005 Al Haqlaniyah, Iraq)
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