Various so-called Greek Catholic churches, Uniates, are not Orthodox churches, Alexandria and similar monophysite, the Maronite Church and so on, are in communion with Rome since the 15th century (following the so-called "re-union" in Florence).
Orthodox Churches are those churches that are in communion with the See of Constantiople. Others are either heretic churches that broke off early in Christian history, or those that joined the Roman Carholic Church at a later date by accepting Latin theological innovations.