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Closed System Opens Way for More Practical Fuel Cell
Scientific American ^ | January 19, 2007 | David Biello

Posted on 01/20/2007 1:08:22 AM PST by neverdem

Using the water produced by a fuel cell to regulate the flow of hydrogen, researchers have made it act like an internal combustion engine--the more hydrogen you put in, the more power you get out

Fuel cells powered by hydrogen are delicate systems. Too little water in the system and the special membranes that allow electricity to be generated dry up, shutting the chemical reaction down. Too much water and the droplets can block the hydrogen gas from interacting with the electrodes, shutting the chemical reaction down. But researchers at Princeton University have discovered ways to make such fuel cells hardier by making them both self-draining and self-regulating, according to a paper in the February Chemical Engineering Science. Claire Woo, an undergraduate student in the lab of chemical engineer Jay Benziger, attempted to find a way to make the lab's patented self-draining fuel cell 100 percent efficient, using just as much hydrogen gas as was supplied. Typical commercial fuel cells only use up to 40 percent of the hydrogen and require recycling systems to bring unused gas back into the reaction chamber. Instead of such a recycling system, Woo added a water tank to collect any excess formed during the chemical reaction. Because gravity already pulls any forming water down into a pool at the bottom of the reaction chamber, Woo could control the overall size of the reaction by the amount of hydrogen gas she allowed to flow into the chamber.

When she increased the flow of hydrogen, it pushed excess water out of the chamber and freed up more of the cell for power production. Conversely, when she added less fuel, more water filled the chamber, blocking part of the reactive surface. "The water would flow in and out of the fuel cell to give a variable area where its size was matched to the power," Benziger says. "Instead of throwing away all of the water, we're letting some of it continue to accumulate."

Of course, this closed fuel cell system is still a prototype on a laboratory bench, but already some of its elements have been found in larger, commercial efforts. For example, Honda's new FCX prototype also relies on a vertical alignment to allow gravity to drain water away. "Honda only had it half right," Benziger notes. "Honda still had to humidify their feeds."

The Princeton prototype does not have to add water because it does not rely on channels to guide the hydrogen gas where it needs to go. Instead, it flows through a series of pillars on its way across the electrode and membrane. By combining such "dry" feeds with no need for recycling—and a way to match power output to fuel input—Benziger and his colleagues have developed a fuel cell that is economical across a broad range of uses. Plus, Benziger says, it has plenty of room to grow: "There is no inherent problem with scaling it up."


TOPICS: Business/Economy; Extended News; News/Current Events; Technical
KEYWORDS: fuelcells; science

Image: COURTESY OF JAY BENZIGER
LIQUID CONTROL: By using its waste water to regulate the size of the reaction, scientists have created a fuel cell that produces more power when it is given more hydrogen. The fuel cell itself is pictured as a little gray box in the middle.

Image: US DEPARTMENT OF ENERGY
1 posted on 01/20/2007 1:08:25 AM PST by neverdem
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To: neverdem

Cool stuff. Very encouraging. Thanks for the post.

Unfortunately we still have to find energy other than foreign oil to make the hydrogen.


2 posted on 01/20/2007 1:14:29 AM PST by D-fendr
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To: neverdem
Why didn't I think of that? It is SO obvious.
3 posted on 01/20/2007 2:20:41 AM PST by Ninian Dryhope ("Bush lied, people dyed. Their fingers." The inestimable Mark Steyn)
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To: D-fendr

Nuclear.


4 posted on 01/20/2007 2:36:20 AM PST by DB
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To: D-fendr

Yes, but it keeps us shovelling millions of taxpayer dollars to those who do not really need the money and blocks the innnovative technology within hydrocarbons from outside the big boys' coaltion that might actually solve the problem. Don't you understand the purpose?


5 posted on 01/20/2007 2:42:21 AM PST by AmericanVictory (Should we be more like them, or they like us?)
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To: DB

Easier: Aluminum cans and lye.


6 posted on 01/20/2007 2:57:27 AM PST by Lexinom (Duncan Hunter 2008 - www.peacethroughstrengthpac.com)
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To: Lexinom

Mentos and a 2 liter of Coke.


7 posted on 01/20/2007 3:03:38 AM PST by ovrtaxt (Well, they wanted to be just like the Dems. Now, they're just like the Dems.)
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To: neverdem

fuel cells are very difficult, even for stationary
application.

will never be practical for mass production cars.


8 posted on 01/20/2007 3:17:15 AM PST by greasepaint
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To: neverdem
The old saying, if you give an infinitesimal number of monkeys an infinitesimal number of typewriters one will type War and Peace or some such book. I would assume the same goes for fuel cell labs.
9 posted on 01/20/2007 3:37:51 AM PST by G-Man 1
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To: neverdem
Digging a hole to shovel money down will give the same results. Still takes more energy to run than it produces.
10 posted on 01/20/2007 6:09:24 AM PST by org.whodat (Never let the facts get in the way of a good assumption.)
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To: greasepaint

Doesn't the fuel cell freeze?


11 posted on 01/20/2007 6:16:41 AM PST by brooklin
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