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Chemicals Were Injected Into Wells, Report Says (During Hydraulic Fracturing by Gas Companies)
New York Times ^ | 04/17/2011 | Ian Urbina

Posted on 04/17/2011 6:24:30 AM PDT by SeekAndFind

Oil and gas companies injected hundreds of millions of gallons of hazardous or carcinogenic chemicals into wells in more than 13 states from 2005 to 2009, according to an investigation by Congressional Democrats.

The chemicals were used by companies during a drilling process known as hydraulic fracturing, or hydrofracking, which involves the high-pressure injection of a mixture of water, sand and chemical additives into rock formations deep underground. The process, which is being used to tap into large reserves of natural gas around the country, opens fissures in the rock to stimulate the release of oil and gas.

Hydrofracking has attracted increased scrutiny from lawmakers and environmentalists in part because of fears that the chemicals used during the process can contaminate underground sources of drinking water.

“Questions about the safety of hydraulic fracturing persist, which are compounded by the secrecy surrounding the chemicals used in hydraulic fracturing fluids,” said the report, which was written by Representatives Henry A. Waxman of California, Edward J. Markey of Massachusetts and Diana DeGette of Colorado.

The report, released late Saturday, also faulted companies for at times “injecting fluids containing chemicals that they themselves cannot identify.”

The inquiry over hydrofracking, which was initiated by the House Energy and Commerce Committee when Mr. Waxman led it last year, also found that 14 of the nation’s most active hydraulic fracturing companies used 866 million gallons of hydraulic fracturing products — not including water. More than 650 of these products contained chemicals that are known or possible human carcinogens, regulated under the Safe Drinking Water Act, or are listed as hazardous air pollutants, the report said.

(Excerpt) Read more at nytimes.com ...


TOPICS: Business/Economy; Culture/Society; News/Current Events
KEYWORDS: chemicals; gas; hydraulicfracture; oil
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To: Russ
My well is located about 100 yds from an active drilling site. In the year they have been drilling under my land they have tested my well three times and there has been no evidence of contamination. Likewise for all my neighbors surrounding the site...

There was another thread on this last night. I pointed out then that this was a pure propaganda piece by the AP. Now a propaganda piece by the AP and gladly given legs by the New York Times.

Read the story carefully. The AP wrote it in such a way that makes one THINK they are talking about evil energy producers have leaked/injected the fluid mixture used in fracking into WATER wells. This assumption would be incorrect. In referring to WELLS, the AP actually means this fluid mixture is injected into the natural gas or oil WELL itself. They just wrote it to make you think it was water wells being affected

61 posted on 04/17/2011 9:21:57 AM PDT by VeniVidiVici (The last Democrat worth a damn was Stalin. He purged his whole Party.)
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To: Scythian
You are ignorant. Gasoline has from 20-30% benzene in it: http://www.elmhurst.edu/~chm/vchembook/515gasolinefs.html

E.P.A. Limits the Benzene in Gasoline by 2011

62 posted on 04/17/2011 9:35:59 AM PDT by epithermal
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To: 9422WMR

Some people think DHMO is a big joke. Check out the official Material Safety Data Sheet for DHMO:

http://www.dhmo.org/msdsdhmo.html

Visit the DHMO website: http://www.dhmo.org/ for the complete story.


63 posted on 04/17/2011 9:46:15 AM PDT by Lonesome in Massachussets (Somewhere in Kenya a village is missing its idiot)
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To: milwguy
As long as the drilling company uses proper procedures in lining the well with stell casing before fracking, the chance of these chemicals getting into the water bearing areas far above is 0.

Can you provide me the contact information for a single professional geologist or hydrogeologist who believes this statement? I suppose there are some who have never installed or dealt with wells before, but to assume that casings and groutings are 100% is someone with little experience, IMO.

64 posted on 04/17/2011 10:23:39 AM PDT by Gondring (Paul Revere would have been flamed as a naysayer troll and told to go back to Boston.)
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To: Robert A. Cook, PE

You have never had a casing or grouting failure in a well? How many wells have you installed?


65 posted on 04/17/2011 10:24:27 AM PDT by Gondring (Paul Revere would have been flamed as a naysayer troll and told to go back to Boston.)
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To: calico_thompson
The EPA actually permits over 500 hazardous material disposal wells in the US that handle foul discharges from Petroleum Refining, Metal Production, Chemical Production, Pharmaceutical Production, Commercial Disposal, Food Production, and Municipal Wastewater Treatment.

And they have to go through a permitting process that frac wells skirt.

If shale-gas fracking is so safe, why the fear of it getting the same scrutiny as other operations?

66 posted on 04/17/2011 10:29:08 AM PDT by Gondring (Paul Revere would have been flamed as a naysayer troll and told to go back to Boston.)
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To: Gondring

try this article, pretty much sums up my points

http://www.wyomingnews.com/articles/2011/04/10/news/19local_04-10-11.txt

The Environmental Protection Agency may conduct a study in Laramie County on the potential dangers to groundwater of hydraulic fracturing.

“Fracking” involves the pressurized injection of water and chemicals into geologic formations to increase the volume of natural gas and/or oil that can be extracted.

“To help ensure that energy production does not come at the expense of public health, EPA scientists are undertaking a study of this practice to better understand any potential impacts it may have on drinking water resources,” an EPA statement says.

EPA has not made a final decision on whether the study will be conducted in Laramie County, which is poised to see significant oil development from the Niobrara shale formation.

Laramie County resident Barry Bruns said he thinks hydraulic fracturing is safe as long as it is done properly.

Bruns, who owns the surface rights on his property but not the mineral rights, said his property values would be devastated if his well became contaminated.

He added that it is “worthwhile” for EPA to conduct the study.

John Wagner, head of the water quality division at the state Department of Environmental Quality, said fracking should not pose a danger to water wells if the process follows DEQ, health department and Wyoming Oil and Gas Commission standards.

Generally, water wells are a few hundred feet deep; fracking occurs at about 7,000 feet. This provides about a mile of separation between the wells and the fracking.

Wagner said he would be more concerned about a septic tank contaminating a water well than fracking.


67 posted on 04/17/2011 10:42:18 AM PDT by milwguy
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To: VeniVidiVici

The issue of Hyrdaulic Fracturing has been going on and on in New York State for YEARS.

The New York City watershed includes a large area of the Marcellus shale formation.

The NYC Dept. of Environmental Protection’s position: “While DEP is mindful of the potential economic opportunity that this represents for the State, hydraulic fracturing poses an unacceptable threat to the unfiltered water supply of nine million New Yorkers and cannot safely be permitted with the New York City watershed.”

The New York State assembly voted 93 to 43, Nov. 30, 2010, to place a moratorium or freeze on hydraulic fracturing to give the state more time to undertake safety and environmental concerns.

Had it been allowed, they estimated at least 6,000 jobs created in NY State.


68 posted on 04/17/2011 10:43:30 AM PDT by SeekAndFind
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To: epithermal; Scythian
You are ignorant. Gasoline has from 20-30% benzene in it: http://www.elmhurst.edu/~chm/vchembook/515gasolinefs.html

Sorry, but it generally has less than 1% by volume, but certainly less than 5%. IIRC, the initial limit your article mentions is 1.3% and then 0.6% later.

And some concerns about benzene in water is that the ingestion of contaminated water takes in more than the inhalation pathway, plus the intrusion of benzene vapor into occupied structures, where the exposures are concentrated because of low air-exchange.

69 posted on 04/17/2011 10:44:02 AM PDT by Gondring (Paul Revere would have been flamed as a naysayer troll and told to go back to Boston.)
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To: taildragger; epithermal; thackney
Show me a list of chemicals

State agencies have released this information. For example, in New York State, it was a scientific and economic development agency (NYSERDA), not the regulatory agency, that commissioned reports from various sources to support the Generic Environmental Impact Statement. For water-related issues, URS Corporation provided the research (PDF). Note that URS Corporation is a consultant to drilling companies, so any bias would be pro-drilling. The draft GEIS is here.

Other states (e.g., Pennsylvania) have looked at MSDSs used by the drilling sites, although this list had to be pared down because non-downhole chemicals still have MSDSs. Still, many are carcinogens...and no matter how many "food" ingredients you put into it, it doesn't mean that the carcinogens in it will suddenly be "overruled" by all the gummi bears you included.

I know that the Democrats of these states are hoping that shale gas will get them out of their irresponsible budget messes, but even conservative geologists are starting to reverse their support as more information comes out.

Remember, Halliburton even admitted only a couple of years ago that they were still using diesel fuel to frack, despite promises given years earlier that they wouldn't do that anymore. Fortunately, they seem to be developing improvements, such as the CleanStim system (h/t epithermal).

Note: I have personal and professional interests that would be promoted by the increased exploitation of shale gas. But I am also a man of integrity.

70 posted on 04/17/2011 10:46:01 AM PDT by Gondring (Paul Revere would have been flamed as a naysayer troll and told to go back to Boston.)
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To: taildragger
RE: Show me a list of chemicals.

(Extracted from http://www.dec.ny.gov/docs/materials_minerals_pdf/ogdsgeischap5.pdf)

CAS Number Chemical Constituent
2634-33-5 1,2 Benzisothiazolin-2-one / 1,2-benzisothiazolin-3-one
95-63-6 1,2,4 trimethylbenzene
123-91-1 1,4-Dioxane
3452-07-1 1-eicosene
629-73-2 1-hexadecene
112-88-9 1-octadecene
1120-36-1 1-tetradecene
10222-01-2 2,2 Dibromo-3-nitrilopropionamide, a biocide
27776-21-2 2,2'-azobis-{2-(imidazlin-2-yl)propane}-dihydrochloride
73003-80-2 2,2-Dobromomalonamide
15214-89-8 2-Acrylamido-2-methylpropane sulphonic acid sodium salt polymer
46830-22-2 2-acryloyloxyethyl(benzyl)dimethylammonium chloride
52-51-7 2-Bromo-2-nitro-1,3-propanediol
111-76-2 2-Butoxy ethanol
1113-55-9 2-Dibromo-3-Nitriloprionamide (2-Monobromo-3-nitriilopropionamide)
104-76-7 2-Ethyl Hexanol
67-63-0 2-Propanol / Isopropyl Alcohol / Isopropanol / Propan-2-ol
26062-79-3 2-Propen-1-aminium, N,N-dimethyl-N-2-propenyl-chloride, homopolymer
9003-03-6 2-propenoic acid, homopolymer, ammonium salt
25987-30-8 2-Propenoic acid, polymer with 2 p-propenamide, sodium salt / Copolymer of acrylamide and sodium acrylate
71050-62-9 2-Propenoic acid, polymer with sodium phosphinate (1:1)
66019-18-9 2-propenoic acid, telomer with sodium hydrogen sulfite
107-19-7 2-Propyn-1-ol / Propargyl alcohol
51229-78-8 3,5,7-Triaza-1-azoniatricyclo[3.3.1.13,7]decane, 1-(3-chloro-2-propenyl)-chloride,
115-19-5 3-methyl-1-butyn-3-ol
127087-87-0 4-Nonylphenol Polyethylene Glycol Ether Branched / Nonylphenol ethoxylated / Oxyalkylated Phenol
64-19-7 Acetic acid
68442-62-6 Acetic acid, hydroxy-, reaction products with triethanolamine
108-24-7 Acetic Anhydride
67-64-1 Acetone
79-06-1 Acrylamide

71 posted on 04/17/2011 10:54:26 AM PDT by SeekAndFind
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To: SeekAndFind
Thank you sir......

I have an old friend that is a hazmat guy @ the chemical plant level. I need to contact him on this subject and see how bad some of these are... Thanks again!

72 posted on 04/17/2011 11:06:22 AM PDT by taildragger (( Palin / Mulally 2012 ))
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To: Gondring

BWHAHAHA! I believe your numbers are closer, but I didn’t take the time to find any better data. It has been many years since I did any LUST work, but I always remember the people that complained about cleaning up their leaks because they were breathing benzene every time they filled their car up. I did a little better research and found this:

“overall average reported benzene levels are expected to decrease from 1.05 volume percent (vol%) in 2007 to 0.59 vol% in 2015”

http://www.epa.gov/oms/regs/toxics/420r08022.pdf

As for the toxicology of benzene, I agree I would much rather breath a little than drink a little. I did notice when I Googled that there were a few studies of service station attendants versus benzene exposure.


73 posted on 04/17/2011 11:10:27 AM PDT by epithermal
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To: SeekAndFind
The booming natural gas industry in Pennsylania is going to take a huge hit as a result of this development.

There is no good reason for the natural gas industry in Pennsylvania -- or anywhere else -- taking any sort of a hit.

Fracking has been a common oil patch practice in Texas during the fifties.

And, aside from a surface spill, the number of times a potable water source has been contaminated is: never!

Even surface spills don't happen any longer, since the industry has taken steps to contain such spills at the wellhead.

Fracking chemicals are injected into strata that are usually around 10,000 feet underground. Hydrocarbons have never bfound in association with potable water. And hydrocarbons and fracking chemicals don't migrate thousands of feet uphill to where potable water may be found.

This report is politically-motivated and without any scientific merit whatsoever. It is simply a ploy to discredit the industry and make hydrocarbon fuels even more expensive and in shorter supply in the USA.

Or, in a word, it's bullshit.

74 posted on 04/17/2011 11:24:46 AM PDT by okie01 (THE MAINSTREAM MEDIA: Ignorance On Parade)
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To: Flavius
Fresh water table ought to be free of playing with.

The fresh water table is 8-12,000 feet of impermeable rock, shale and chalk away from where the fracking is taking place.

In over fifty years of fracking history, no potable water source has ever been contaminated by the process.

75 posted on 04/17/2011 11:35:17 AM PDT by okie01 (THE MAINSTREAM MEDIA: Ignorance On Parade)
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To: okie01
In over fifty years of fracking history, no potable water source has ever been contaminated by the process

Most telling statement on the board.

Looks like Waxman/Markey sense the "drill Baby drill" mantra is going to gain much steam in coming years and they're frantically trying to head it off whichever lying way they can.

76 posted on 04/17/2011 12:21:14 PM PDT by Siena Dreaming
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To: Lonesome in Massachussets
Not only the fearsome dihydrogen monoxide (found in astonishing quantities in everything from acid rain to mother's milk, and even in beverages and foodstuffs intended for human consumption, quelle horreur), but also compounds such as sodium lauryl sulfate and quaternary ammonium salts... which you can find in any bottle of baby shampoo.
77 posted on 04/17/2011 1:12:14 PM PDT by Tenniel2 (Ignore politics and you'll end up being governed by your inferiors. -- Plato)
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To: okie01

That’s fantastic . Again there are trillions of cubic feet of methane off shore in middle of nowhere the ocean desert.

They are using Fresh water to pump down .


78 posted on 04/17/2011 1:26:13 PM PDT by Flavius (What hopes for victory, Gaius Crastinus? What grounds for encouragement ?)
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To: Ernest_at_the_Beach; AdmSmith; AnonymousConservative; Berosus; bigheadfred; ColdOne; ...

Thanks SeekAndFind.
according to an investigation by Congressional Democrats



79 posted on 04/17/2011 5:43:43 PM PDT by SunkenCiv (Thanks Cincinna for this link -- http://www.friendsofitamar.org)
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Whoops! Thanks Robert A. Cook, PE!


80 posted on 04/17/2011 7:55:14 PM PDT by SunkenCiv (Thanks Cincinna for this link -- http://www.friendsofitamar.org)
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