Posted on 10/09/2018 7:29:46 PM PDT by BenLurkin
[R]esearchers at the Max Planck Institute for the Structure and Dynamics of Matter are reporting "ultrabright" electron sources with sufficient brightness to literally light up atomic motions in real timeat a time scale of 100 femtoseconds, making these sources particularly relevant to chemistry because atomic motions occur in that window of time.
After seeing the first atomic movies of phase transitions in bulk thin films using high-energy (100 kilovolt) electron bunches, the researchers wondered if they could achieve atomic resolution of surface reactionsoccurring within the first few monolayers of materialsto gain a better understanding of surface catalysis.
So they devised a low-energy (1-2 kilovolt) time-resolved electron diffraction concept of using fiber optics for miniaturization and the ability to stretch the electron pulse, then apply streak camera technology to potentially obtain subpicosecond temporal resolutiona difficult feat within the low-electron energy regime.
Of the myriad possible nuclear configurations, the group discovered that the system collapses to just a few key modes that direct chemistry and that a reduction in dimensionality that occurs in the transition state or barrier-crossing region can be inferred. "We see it directly with the first atomic movies of ring closing, electron transfer and bond breaking," said Miller.
(Excerpt) Read more at phys.org ...
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