Free Republic
Browse · Search
News/Activism
Topics · Post Article

Skip to comments.

Nanotubes Crank Out Hydrogen
Technology Research News/Fuel Cell Today ^ | 27 January 2005

Posted on 01/31/2005 11:44:25 AM PST by anymouse

Pure hydrogen fuel is non-polluting. Current methods of extracting hydrogen, however, use energy derived from sources that pollute. Finding ways to use the sun's energy to split water to extract hydrogen would make for a truly clean energy source.

Several research efforts are using materials engineered at the molecular scale to tap the sun as an energy source to extract hydrogen from water.

Researchers from Pennsylvania State University have constructed a material made from titanium dioxide nanotubes that is 97 percent efficient at harvesting the ultraviolet portion of the sun's light and 6.8 percent efficient at extracting hydrogen from water.

The material is easy to make, inexpensive, and photochemically stable, according to the researchers. The 97 percent efficiency is the highest reported, according to the researchers. There is one catch -- only five percent of the sun's energy is ultraviolet light.

The researchers are working to find a way to shift the response of the nanotube arrays into the visible spectrum.

The key to making titanium dioxide nanotubes that efficiently harvest the energy from light is controlling the thickness of the nanotube walls, according to the researchers. Nanotubes 224 nanometers long with 34-nanometer-thick walls are three times more efficient than those that are 120 nanometers long with 9-nanometer-thick walls.

The researchers made the titanium dioxide nanotube material by mixing titanium with acid and electrifying the mixture, which caused the tiny tubes to grow, then heating them to cause the material to crystallize.

The material could be ready for practical use in two to five years, according to the researchers. The work appeared in the January 12, 2005 issue of Nano Letters.


TOPICS: Business/Economy; News/Current Events; Technical; US: Pennsylvania
KEYWORDS: buckyballs; catalysis; elonmusk; energy; falcon9; falconheavy; hydrogen; nanotech; nanotechnology; nanotubes; pennstate; pennsylvania; research; science; solarenergy; spacex; sun; titaniumdioxide; universtity; water
Navigation: use the links below to view more comments.
first 1-2021-4041-49 next last
Interesting technology to watch.
1 posted on 01/31/2005 11:44:26 AM PST by anymouse
[ Post Reply | Private Reply | View Replies]

To: anymouse
On the other hand using coal fired furnaces to to generate electricity to hydrolyze water to create Hydrogen and Oxygen is probably what is going to be done for quite some time and makes no sense.
2 posted on 01/31/2005 11:52:27 AM PST by Mikey_1962
[ Post Reply | Private Reply | To 1 | View Replies]

To: anymouse

I think this will be OBE, specifically thermal depolymerization.


3 posted on 01/31/2005 12:03:34 PM PST by Meldrim
[ Post Reply | Private Reply | To 1 | View Replies]

To: anymouse

later read bump


4 posted on 01/31/2005 12:05:28 PM PST by investigateworld (Babies= A sure sign He hasn't given up on mankind!)
[ Post Reply | Private Reply | To 1 | View Replies]

To: anymouse

Pah!

The flux capacitor in my DeLorean has been doing this for twenty years.

5 posted on 01/31/2005 12:11:23 PM PST by stinkerpot65
[ Post Reply | Private Reply | To 1 | View Replies]

To: anymouse

I still think hydrogen is a non-starter. No matter how efficient you get at producing it, the low energy density and near-impossibily of storing it for any significant length of time (it seeps through damn near everything) makes it no match for other fuels.


6 posted on 01/31/2005 12:17:49 PM PST by Squawk 8888 (With enemies like Michael Moore, who needs friends?)
[ Post Reply | Private Reply | To 1 | View Replies]

To: stinkerpot65

How many grams to the mile does that Delorian get? :)


7 posted on 01/31/2005 12:18:25 PM PST by anymouse
[ Post Reply | Private Reply | To 5 | View Replies]

To: Mikey_1962

Those wonderful "zero emission" electric cars and fuel cell vehicles really aren't "zero emission" at all. They just move their emissoions from where they're operated to to electric power plants producing the electricity required to charge their batteries or manufacture the hydrogen by electrolysis.


8 posted on 01/31/2005 12:20:40 PM PST by libstripper
[ Post Reply | Private Reply | To 2 | View Replies]

To: Mikey_1962
On the other hand using coal fired furnaces to to generate electricity to hydrolyze water to create Hydrogen and Oxygen is probably what is going to be done for quite some time and makes no sense.

Actually it makes lots of sense. It is much easier to put scrubbers on one plant than to maintain emissions on millions of cars.

9 posted on 01/31/2005 12:21:52 PM PST by Only1choice____Freedom ("Do not pray for tasks equal to your powers; pray for powers equal to your tasks,"-President Bush)
[ Post Reply | Private Reply | To 2 | View Replies]

To: anymouse

Of course, it still suffers from the same problem that all solar sources do, namely, the low power density of sunlight. At 1 kW per square meter, it would take 1 square kilometer of a 100% conversion efficiency process, at the equator (when the sun is directly overhead) to generate 1 GW - at noon. Away from the equator, away from noon, and if your process isn't 100% efficient, it would take more land area than that to make 1 GW. That's a lot of land for only a modestly powerful power plant.


10 posted on 01/31/2005 12:23:23 PM PST by coloradan (Hence, etc.)
[ Post Reply | Private Reply | To 1 | View Replies]

To: libstripper

One point of the conversion is to move our oil dependency over to natural gas dependency.


11 posted on 01/31/2005 12:25:41 PM PST by RightWhale (Please correct if cosmic balance requires.)
[ Post Reply | Private Reply | To 8 | View Replies]

To: anymouse
If we destroy the ozone layer we could cause more ultraviolet light to strike the surface of the Earth. This would enable this technology to be more efficient so we don't have to release so many greenhouse gasses!
12 posted on 01/31/2005 12:25:55 PM PST by rightsmart (Was W '04, now W '0N)
[ Post Reply | Private Reply | To 1 | View Replies]

To: Meldrim

TDP OH YEAH!!!!!!!


13 posted on 01/31/2005 12:26:22 PM PST by petro45acp (Democrat = socialist. Say it loud, say it often, and VOTE!!)
[ Post Reply | Private Reply | To 3 | View Replies]

To: Only1choice____Freedom
It is much easier to put scrubbers on one plant than to maintain emissions on millions of cars.

What kind of emissions is produced by hydrogen fuel?

14 posted on 01/31/2005 12:28:42 PM PST by Ol' Dan Tucker
[ Post Reply | Private Reply | To 9 | View Replies]

To: Only1choice____Freedom

You are forgetting about the efficiency loss at each step. After all the conversions you are probably at a whopping 3% efficiency


15 posted on 01/31/2005 12:38:55 PM PST by Mikey_1962
[ Post Reply | Private Reply | To 9 | View Replies]

To: coloradan

I'd bet that your average 1000 MW coal or nuclear station has a bigger footprint than 1 square km. But those darned "sun angle", "nighttime", and "cloudy day" issues...those are tough indeed to overcome.


16 posted on 01/31/2005 12:39:26 PM PST by Lekker 1 (A government policy to rob Peter to pay Paul can be assured of the support of Paul [G.B. Shaw])
[ Post Reply | Private Reply | To 10 | View Replies]

To: coloradan

Actually, keeping it at the equator still wouldn't maintain maximum capture. You'd have to continuously migrate it between the two tropics. /nitpick


17 posted on 01/31/2005 12:51:26 PM PST by Squawk 8888 (With enemies like Michael Moore, who needs friends?)
[ Post Reply | Private Reply | To 10 | View Replies]

To: anymouse
From the article: "The 97 percent efficiency is the highest reported, according to the researchers. There is one catch -- only five percent of the sun's energy is ultraviolet light. "

In less-biased engineering terms, we would say that this process for converting sunlight to an alternate form of energy is 5% efficient. But why let realistic calculations get in the way of a good story.

18 posted on 01/31/2005 12:51:49 PM PST by William Tell
[ Post Reply | Private Reply | To 1 | View Replies]

To: Only1choice____Freedom
"Actually [making hydrogen by using coal powered electricity] makes lots of sense"

Even when compressed a thousand times atmospheric pressure, hydrogen occupies 5 times the volume of gasoline. Where do you propose storing it in a vehicle?

19 posted on 01/31/2005 12:56:41 PM PST by norwaypinesavage
[ Post Reply | Private Reply | To 9 | View Replies]

To: anymouse

Depending on how big, how cheap and how resistant to contamination these gadgets are in practice, burning the hydrogen to make water might be a useful method of desalinization.


20 posted on 01/31/2005 1:22:15 PM PST by Grut
[ Post Reply | Private Reply | To 1 | View Replies]


Navigation: use the links below to view more comments.
first 1-2021-4041-49 next last

Disclaimer: Opinions posted on Free Republic are those of the individual posters and do not necessarily represent the opinion of Free Republic or its management. All materials posted herein are protected by copyright law and the exemption for fair use of copyrighted works.

Free Republic
Browse · Search
News/Activism
Topics · Post Article

FreeRepublic, LLC, PO BOX 9771, FRESNO, CA 93794
FreeRepublic.com is powered by software copyright 2000-2008 John Robinson