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Element 114 confirmed
Chemistry World ^ | 30 September 2009 | Phillip Broadwith

Posted on 10/03/2009 7:46:52 AM PDT by neverdem

US scientists have confirmed the discovery of element number 114, first made over a decade ago by a team in Russia. By smashing a high energy beam of calcium-48 ions into a plutonium-242 target, the US team managed to detect two nuclei of element 114, which is predicted by some to be bordering the so-called 'island of stability' for superheavy atoms.

Yuri Oganessian and his team at Dubna, Russia, were the first to claim to have created nuclei of element 114 - but any such claim has to be thoroughly verified and the experiments repeated independently before the element can be considered for admission to the periodic table. Heino Nitsche and a team from the University of California at Berkeley spent eight days bombarding their plutonium target with calcium ions in an attempt to create the elusive element 114. 'We expected to see maybe six to eight nuclei, but we only found two!' says Nitsche. He adds that the characteristic decay sequences and energies matched very well with the Russian data for two isotopes of element 114.

Heino Nitsche and his team

Heino Nitsche and his team confirmed the discovery of element 114

© Roy Kaltschmidt, Berkeley

Like the Russians before them, Nitsche and his team used a high energy beam of 48Ca, which has eight extra neutrons compared to the most abundant isotope of calcium, 40Ca. When a 48Ca nucleus collides with a 242Pu nucleus, there is a small chance that the nuclei will fuse to create a compound nucleus with 114 protons (20 from calcium and 94 from plutonium) and 176 neutrons, explains Nitsche, 'but this is unstable and evaporates either three or four neutrons to make 287114 or 286114.'

This neutron evaporation is one of the reasons why it is difficult to confirm exactly what isotope is formed in a fusion experiment, says Nitsche, 'You know how they decay, but you can't be 100 per cent sure if the number of neutrons that evaporates is correct because you're not measuring the mass.' The fact that some of the decay products can be unknown isotopes or even unknown elements adds to the difficulty, he adds.

Oganessian says he is very happy that Nitsche's group have reproduced his team's result. 

Nitsche suggests that his confirmation of the data for 114 might be enough evidence for the International Union of Pure and Applied Chemistry (Iupac) to officially recognise the Russian group as its discoverers, which would allow them to propose a name for the element, but Oganessian is stoical about the process: 'Iupac will need to check the priority and accuracy of the discovery, and that's a procedure that takes time - they have only just finished with element 112, and are still discussing the name and symbol.' He adds that it will probably not be until the end of the year that they start discussing claims to the heavier elements, including 114 and 116.

Island life

Confirmation of the existence and lifetimes of isotopes of element 114 is a big step in the hunt for a tantalising 'island of stability' predicted by theoreticians, where the lifetimes of super-heavy elements could be measured in hours, days or even millions of years. 'There are some calculations that say a nucleus with 114 protons and 184 neutrons would be stable,' says Nitsche. The two isotopes confirmed by the Berkeley group, 286114 and 287114, have half-lives of 0.13s and 0.5s respectively, but the Russian data for a heavier isotope, 289114 - made by bombarding 244Pu with 48Ca, suggest a half-life of 2.6s. 'The half-lives increase as we get closer to 184 neutrons,' says Nitsche, '2.6 seconds is an absolute eternity - people are starting to plan chemistry experiments now, to see if 114 behaves like the elements above it in the periodic table.'

island of stability

Scientists are tantalisingly close to the island of stability

But Nitsche points out that they are still at least nine neutrons away from the predicted point of stability, and to make heavier isotopes is not easy. 'Some people say the island might not be until elements 120 or 126, or there might simply be a continuous increase in stability.' He adds that experiments to make heavier elements are very important to aid theoreticians trying to understand the nucleus and make sensible predictions. Oganessian is also keen to find heavier elements, saying that his group has just begun a collaboration with scientists in the US to try and make element 117.

 

References

L Stavsetra et alPhys. Rev. Lett., 2009, 103, 132502 (DOI: 10.1103/PhysRevLett.103.132502)

Also of interest

Very heavy metal

Chemists arrive at the island of stability

02 May 2007

Despite predictions of exotic properties, 'superheavy' element 112 behaves like one of the family



TOPICS: Science
KEYWORDS: chemistry; element; element114; islandofstability; physics; science; stringtheory; superheavyatoms; ununquadium
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1 posted on 10/03/2009 7:46:53 AM PDT by neverdem
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To: AdmSmith; bvw; callisto; ckilmer; dandelion; ganeshpuri89; gobucks; KevinDavis; Las Vegas Dave; ...

· String Theory Ping List ·
Cat Physicist
· View or Post in 'blog · Join · Bookmark · Topics · post a topic · subscribe · Google ·

2 posted on 10/03/2009 7:50:42 AM PDT by SunkenCiv (https://secure.freerepublic.com/donate/__Since Jan 3, 2004__Profile updated Monday, January 12, 2009)
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To: neverdem

I want to understand. This is important stuff, but I’m afraid my tired old brain is so filled with air that it quickly rises to the top instead of descending into the depths of knowledge.


3 posted on 10/03/2009 7:51:16 AM PDT by devane617 (Free HOLLY101 -- After all, she is right.)
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To: neverdem

Um....I think I’ve had some element 114 on the bottom shelf of my refrigerator for about three years now.


4 posted on 10/03/2009 7:51:45 AM PDT by Krankor
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To: neverdem

Chuck Norris destroyed the periodic table, because Chuck Norris only recognizes the element of surprise.


5 posted on 10/03/2009 7:52:51 AM PDT by reagan_fanatic (Hope....Change...Bullsh*t)
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To: neverdem

Darned attractive for a group of scientists. The young lady in the center is particularly easy on he eye.


6 posted on 10/03/2009 7:53:15 AM PDT by B-Chan (Catholic. Monarchist. Texan. Any questions?)
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To: Krankor

Yikes, is that what that gooey stuff is? My next question, is is toxic or is it worth something?


7 posted on 10/03/2009 7:53:23 AM PDT by Ditter
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To: Ditter

Well, I’d like to check, but I don’t want to disturb elements 1 thru 113.


8 posted on 10/03/2009 7:56:52 AM PDT by Krankor
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To: neverdem
I am going to have to go out and buy a new chemistry book.

This is a bit esoteric for me, but I still love it.

9 posted on 10/03/2009 8:02:47 AM PDT by Radix (Obama represents CHAINS for posterity.)
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To: reagan_fanatic
Who does the boogey man check to see is under his bed? Chuck Norris.

Thread hijack attempt.

5.56mm

10 posted on 10/03/2009 8:05:24 AM PDT by M Kehoe
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To: neverdem; SunkenCiv
           ^----- Composed of 99% Hottium plus trace elements

11 posted on 10/03/2009 8:07:43 AM PDT by martin_fierro (< |:)~)
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To: Krankor

Look deeper, it hides under the bottom bin. You have to slide out the bin to search out the 114.


12 posted on 10/03/2009 8:11:54 AM PDT by MHGinTN (Dems, believing they cannot be deceived, it is impossible to convince them when they are deceived.)
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To: FredZarguna; decimon; snarks_when_bored; Myrddin; Wonder Warthog; Robert A. Cook, PE
Like, *PING*, dudes.

Cheers!

13 posted on 10/03/2009 8:17:16 AM PDT by grey_whiskers (The opinions are solely those of the author and are subject to change without notice.)
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To: neverdem

Yeah, that’s nice. Got a number for the hottie in the middle ?


14 posted on 10/03/2009 8:24:56 AM PDT by fieldmarshaldj (~"This is what happens when you find a stranger in the Alps !"~~)
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To: Krankor

Aw man! You’ve got it all! I don’t know whether i should try to become your best friend or avoid you.


15 posted on 10/03/2009 9:02:52 AM PDT by Ditter
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To: neverdem

http://www.youtube.com/watch?v=DYW50F42ss8
Tom Lehrer CHEMISTRY element song


16 posted on 10/03/2009 9:06:37 AM PDT by Liberty Valance (Keep a simple manner for a happy life :o)
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To: neverdem

governmentium:

A major research institution (MRI) has recently announced the discovery of the heaviest chemical element yet known to science. The new element has been tentatively named Governmentium. Governmentium has 1 neutron, 12 assistant neutrons, 75 deputy neutrons, and 224 assistant deputy neutrons, giving it an atomic mass of 312. These 312 particles are held together by forces called morons, which are surrounded by vast quantities of lepton-like particles called peons. Since governmentium has no electrons, it is inert. However, it can be detected as it impedes every reaction with which it comes into contact. A minute amount of governmentium causes one reaction to take over four days to complete when it would normally take less than a second. Governmentium has a normal half-life of three years; it does not decay, but instead undergoes a reorganization in which a portion of the assistant neutrons and deputy neutrons exchange places. In fact, governmentium’s mass will actually increase over time, since each reorganization will cause some morons to become neutrons, forming isodopes.

This characteristic of moron-promotion leads some scientists to speculate that governmentium is formed whenever morons reach a certain quantity in concentration. This hypothetical quantity is referred to as Critical Morass.


17 posted on 10/03/2009 9:14:26 AM PDT by tired1 (When the Devil eats you there's only one way out.)
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To: neverdem

Will it be named “Unobtanium”?


18 posted on 10/03/2009 2:29:48 PM PDT by QBFimi (When gunpowder speaks, beasts listen.)
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To: QBFimi
"Will it be named “Unobtanium”?"

Nope, close.

Obamaium.

19 posted on 10/03/2009 2:34:04 PM PDT by Landru (Arghh, Liberals are trapped in my colon like spackle or paste.)
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To: neverdem

Two observations:

As noted above, both young women are easy on the eyes.

Aside from that, unless they are discovering the elements Admantium or Naquadah what practical use is it?


20 posted on 10/03/2009 3:21:16 PM PDT by GreenLanternCorps ("Barack Obama" is Swahili for "Jimmy Carter".)
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