Free Republic
Browse · Search
News/Activism
Topics · Post Article

Skip to comments.

A Rising Tide of Acid Off California
ScienceNOW ^ | 14 June 2012 | Robert F. Service

Posted on 06/25/2012 1:27:18 AM PDT by neverdem

Foreboding. Animation of changes in ocean acidification over time in the California Current System. The left side shows the depth of aragonite saturation, and the right side shows the surface ocean pH.
Courtesy of Nicolas Gruber and Claudine Hauri

Humanity's use of fossil fuels sends 35 billion metric tons of carbon dioxide into the atmosphere every year. That has already begun to change the fundamental chemistry of the world's oceans, steadily making them more acidic. Now, a new high resolution computer model reveals that over the next 4 decades, rising ocean acidity will likely have profound impacts on waters off the West Coast of the United States, home to one of the world's most diverse marine ecosystems and most important commercial fisheries. These impacts have the potential to upend the entire marine ecosystem and affect millions of people dependent upon it for food and jobs.

About one-third of the carbon dioxide (CO2) humans pump into the atmosphere eventually diffuses into the surface layer of the ocean. There, it reacts with water to create carbonic acid and release positively charged hydrogen ions that increase the acidity of the ocean. Since preindustrial times, ocean acidity has increased by 30%. By 2100, ocean acidity is expected to rise by as much as another 150%.

Declining pH of seawater reduces the amount of carbonate ions in the water, which many shell-building organisms combine with calcium to create the calcium carbonate that they use to build their shells and skeletons. The lower carbonate availability, in turn, decreases a measure known as the saturation state of aragonite, an easily dissolvable mineral form of calcium carbonate that organisms such as oyster larvae rely on to build their shells. If the aragonite saturation state falls below a value of 1, a condition known as undersaturation, all calcium carbonate shells will dissolve. But trouble starts well before that. If the aragonite saturation state falls below 1.5, some organisms such as oyster larvae are unable to harvest enough aragonite to build shells during the first days of their lives, and they typically succumb quickly.

These changes are particularly worrisome for global ocean regions known as eastern boundary upwelling zones. In these regions, such as those along much of the West Coast of the United States, winds push surface water away from the shore, causing water from the deep ocean to well up. This water typically already has naturally high levels of dissolved CO2, produced by microbes that eat decaying algae and other organic matter and then respire CO2. Along the central Oregon coast, for example, when summer winds blow surface ocean waters offshore, a measure of the amount of CO2 in the water known a partial pressure rises from a few hundred to over 2000, causing ocean acidity to spike.

But oceanographers still didn't have a good handle on how rising atmospheric CO2 levels would interact with CO2 rich waters that upwell naturally. So for their current study, researchers led by Nicolas Gruber, an ocean biogeochemist at the Swiss Federal Institute of Technology in Zurich, decided to look closely at what's likely to happen in an upwelling region known as the California Current System off the West Coast of the United States. They constructed a regional ocean model that ties together what's going on in the atmosphere and the ocean. Because this model focused on the California Current System, Gruber and colleagues were able to give it a resolution 400 times that of conventional global ocean models. In their model, the Swiss team considered different scenarios of CO2 emissions over the next 4 decades and linked these to CO2 produced in the ocean due to respiration.

The buildup of atmospheric CO2 will rapidly increase the amount of undersaturated waters in the upper 60 meters of ocean, where most organisms live, the team reports online today in Science. Prior to industrialization, undersaturation conditions essentially did not exist at this top layer in the ocean. Today, Gruber says, undersaturation conditions exist approximately 2% to 4% of the time. But by 2050, surface waters of the California Current System will be undersaturated for half of the year.

Perhaps just as bad, however, aragonite saturation will fall below 1.5 for large chunks of each year. This could spell doom for Pacific oysters, a $110 million-per-year industry on the West Coast, as well as for other shell-building organisms that are sensitive to changes in ocean acidity, says Sue Cudd, owner of the Whiskey Creek Shellfish Hatchery on Netarts Bay in Oregon. Another species likely to face difficulty are tiny sea snails known as pteropods, which are a vital food source for young salmon.

The new results are "alarming," says Richard Feely, a chemical oceanographer at the National Oceanic and Atmospheric Administration's Pacific Marine Environmental Laboratory in Seattle, Washington. "It's dramatic how fast these changes will take place."

George Waldbusser, an ocean ecologist and biogeochemist at Oregon State University, Corvallis, says it's not clear precisely how rising acidity will affect different organisms. However, he adds, the changes will likely be broad-based. "It shows us that the windows of opportunity for organisms to succeed get smaller and smaller. It will probably have important effects on fisheries, food supply, and general ocean ecology."


TOPICS: Culture/Society; News/Current Events; US: California
KEYWORDS: biology; carbondioxide; chemistry; oceanacidification
Navigation: use the links below to view more comments.
first previous 1-2021-4041-6061-70 next last
To: Carry_Okie

I don’t know anything either.

But I always thought that more CO2 would mean more photosynthesis, more green plant material. After all, if you want to enhance the production of roses in a greenhouse, you add, that is ADD MORE CO2.

More little plants, microscopic, in the ocean, the more the little animal grow and reproduce, more plankton for the whales and then the whales poop, and poop is more acidic.

Ever drank real old almost spoiled orange juice. It has bacteria and everything that is on the animal side rather than on the plant side....well, they poop and poop is acidic.

Plants on the other hand, give off O2 which is essentially their poop and we can breathe that.

That is why God made plants and animals. I’m not real sure who made liberals.


21 posted on 06/25/2012 3:02:39 AM PDT by Battle Axe (Repent, for the coming of the Lord is nigh.)
[ Post Reply | Private Reply | To 9 | View Replies]

To: samtheman

The fraud has a couple of other dimensions as well....

The World Elite...having created the European and American welfare state mess with gargantuan deficits, had always intended to pay it down with the taxes on carbon-essentially on breathing.

The “scientists” are merely the useful idiots needed to try to bludgeon a reluctant electorate and state legislators with a barrage of hyper-nonsense about the issue.


22 posted on 06/25/2012 3:04:57 AM PDT by mo (If you understand, no explanation is needed. If you don't understand, no explanation is possible.)
[ Post Reply | Private Reply | To 20 | View Replies]

To: Rocky
And, oh boy, another computer model. But this one has 400x better “resolution”, whatever that it.

What that means is that this model is capable of generating 400x larger research grants.

23 posted on 06/25/2012 3:12:09 AM PDT by Fresh Wind ('People have got to know whether or not their president is a crook.' Richard M. Nixon)
[ Post Reply | Private Reply | To 18 | View Replies]

To: mo

Good point. It’s not just about individuals trying to advance their careers by being trained monkeys coming up with novel new ways to dance to the masters’ global warming organ grinder music.

It’s more organized than that. The establishment has a desperate need — in terms of both power politics and economic viability — to make the AGW theory “work”.


24 posted on 06/25/2012 3:13:46 AM PDT by samtheman (http://www.washingtontimes.com/news/2012/jun/21/obamas-socialist-designs/)
[ Post Reply | Private Reply | To 22 | View Replies]

To: Redcloak

For those “scientists” who think a little more acidity in the ocean is harmful, may I suggest that they are the ones who believe in “evolution”.


25 posted on 06/25/2012 3:21:29 AM PDT by gigster (Cogito, Ergo, Ronaldus Magnus Conservatus)
[ Post Reply | Private Reply | To 4 | View Replies]

To: gigster
For those “scientists” who think a little more acidity in the ocean is harmful, may I suggest that they take a piss in the ocean and add some alkali
26 posted on 06/25/2012 3:35:16 AM PDT by mason-dixon (As Mason said to Dixon, you have to draw the line somewhere.)
[ Post Reply | Private Reply | To 25 | View Replies]

To: gigster
For those “scientists” who think a little more acidity in the ocean is harmful, may I suggest that they take a piss in the ocean and add some alkali
27 posted on 06/25/2012 3:35:42 AM PDT by mason-dixon (As Mason said to Dixon, you have to draw the line somewhere.)
[ Post Reply | Private Reply | To 25 | View Replies]

To: Rocky

From over population, to global cooling, to acid rain, to global warming, to climate change, to acid ocean, to...


28 posted on 06/25/2012 3:36:08 AM PDT by CitizenUSA (Why celebrate evil? Evil is easy. Good is the goal worth striving for.)
[ Post Reply | Private Reply | To 18 | View Replies]

To: neverdem
Photobucket
29 posted on 06/25/2012 3:41:32 AM PDT by 2111USMC (Not a hard man to track. Leaves dead men wherever he goes.)
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem

So man makes 35 billion metric tons of CO2 each year? Really? That would be 7 metric tons per man woman and child. This comes to 43 lb. per day per human. I don’t think so


30 posted on 06/25/2012 3:46:56 AM PDT by SampleMan (Feral Humans are the refuse of socialism.)
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem

Guess the scientists have dried up the government atmosphere study teat.
They’ve graphed everything possible.

Time to find a different boogeyman and get the milk flowing again.
New studies, new graphs, new grants. more money.


31 posted on 06/25/2012 3:57:06 AM PDT by Vinnie (A)
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem
Oh, my, I would really expect better from Science.

Since preindustrial times, ocean acidity has increased by 30%. By 2100, ocean acidity is expected to rise by as much as another 150%.

The percentage of pH change makes no sense at all. What does it mean, to use a linear scale to describe a change in logarithmic value?

Declining pH of seawater reduces the amount of carbonate ions in the water, which many shell-building organisms combine with calcium to create the calcium carbonate that they use to build their shells and skeletons. The lower carbonate availability, in turn, decreases a measure known as the saturation state of aragonite, an easily dissolvable mineral form of calcium carbonate that organisms such as oyster larvae rely on to build their shells.

Carbon dioxide dissolves in water to create carbonic acid:

CO2 + H2O <--> H2CO3

H2CO3 then dissociates to become HCO3- and CO32-.

The rightmost chemical in that series is carbonate ion.

All four forms of carbon dioxide exist in aqueous solution, with the proportions determined by pH, temperature, and gaseous concentration of CO2.

(We take advantage of this equilibrium to control our blood pH: when it drops (from increased carbon dioxide production through increased exertion), we breathe faster so as to shed more carbon dioxide and raise the pH.)

More CO2 dissolving in the ocean *will* decrease oceanic pH. That's simple chemistry. But the whole picture is a bit more complicated than that.

All the ionic forms of carbon dioxide (CO2, H2CO3, HCO3-, and CO32-) coexist in an aqueous environment. Since the proportions must stay constant for a given temperature and pressure, removal of carbonate by sea animals causes more carbon dioxide to shift to the other forms. Seaweeds and algae also remove carbon dioxide, causing a shift from the other forms back to carbon dioxide. The process is highly dynamic.

I highly object to the alarmism. The carbon cycle has been operating for millions of years. Atmospheric carbon dioxide levels have increased and decreased periodically for millions of years, with an overall decrease (see my profile: at some point, there won't be enough to sustain life). All carbon dioxide that we use was once in the atmosphere. Sure, it's valuable to know exactly what happens in the ocean during periods of higher and lower carbon dioxide concentrations, but nothing merits getting hysterical over noting a higher or lower concentration right now.

32 posted on 06/25/2012 4:26:17 AM PDT by exDemMom (Now that I've finally accepted that I'm living a bad hair life, I'm more at peace with the world.)
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem

Before I read the article, I have to ask “how the hell did this study come under the title of SCIENCE?”

It should be filed under the category of “FICTION.”

With that said, I will now read the article.....but I already know what’s it’s about.....hint.....GREEN.


33 posted on 06/25/2012 4:28:11 AM PDT by DH (Once the tainted finger of government touches anything the rot begins)
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem
Yes, this is another one of those tricks where their model takes a look at current conditions (which are nebulous at best) and makes them worse over time.

That approach totally discounts mitigating conditions ~ most of which we've not yet discovered, but prior experience tells us are there.

I have a computer model that says that over the next 40 years the California appetite for oysters will disappear due to the failure of the municipal sewage systems as the entire nation of Mexico as as 40% of the population of Central America and most of Columbia relocate to Los Angeles county.

34 posted on 06/25/2012 4:33:57 AM PDT by muawiyah
[ Post Reply | Private Reply | To 6 | View Replies]

To: neverdem
The solution is simple.


35 posted on 06/25/2012 4:34:52 AM PDT by Disambiguator
[ Post Reply | Private Reply | To 1 | View Replies]

To: Rocky
Actually they look at coral ~ tiny animals who come in two varieties ~ cold water and warm water.

Some things really stress them out ~ like, for example, the raising and lowering of the world ocean level by hundreds of feet during and after the Ice Ages (we've had 20 of 'em in recent times).

There are still coral around, and there are scientists who study coral.

This particular model is focused on oysters ~ which is easy ~ and of some commercial interest to somebody somewhere.

Coral are not of much interest to anyone but scientists who study coral.

"They" want your attention so they've threatened something you like ~ presumably oysters.

Actually, I'm not that hot on oysters either ~ more likely to boil up some coral in fact.

36 posted on 06/25/2012 4:42:28 AM PDT by muawiyah
[ Post Reply | Private Reply | To 18 | View Replies]

To: OldMissileer

Swimmers peeing in the ocean will now be fined 50 billion dollars. You get to be the monitor.


37 posted on 06/25/2012 4:42:32 AM PDT by Humble Servant
[ Post Reply | Private Reply | To 12 | View Replies]

To: Fresh Wind

” “will likely have profound impacts”
“have the potential”
“likely to happen”
“could spell doom”
“likely to face difficulty”
“it’s not clear”
“likely be broad based”
“probably have important effects” “

You forgot, “Women and children hardest hit” and “Bush’s fault”.


38 posted on 06/25/2012 4:45:42 AM PDT by Humble Servant
[ Post Reply | Private Reply | To 15 | View Replies]

To: neverdem

Well global warming didn’t work so the hysterocracy needs a new cause. Finally, something they can worry about and march for... Thank heavens the scientists have again come to the rescue saving us from CO2.


39 posted on 06/25/2012 4:47:01 AM PDT by ThePatriotsFlag (Anybody but Obama.)
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem
Now, a new high resolution computer model reveals

BARF, more sudo Science lies.

40 posted on 06/25/2012 5:25:55 AM PDT by Texas Fossil (Government, even in its best state is but a necessary evil; in its worst state an intolerable one)
[ Post Reply | Private Reply | To 1 | View Replies]


Navigation: use the links below to view more comments.
first previous 1-2021-4041-6061-70 next last

Disclaimer: Opinions posted on Free Republic are those of the individual posters and do not necessarily represent the opinion of Free Republic or its management. All materials posted herein are protected by copyright law and the exemption for fair use of copyrighted works.

Free Republic
Browse · Search
News/Activism
Topics · Post Article

FreeRepublic, LLC, PO BOX 9771, FRESNO, CA 93794
FreeRepublic.com is powered by software copyright 2000-2008 John Robinson