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Embracing the Void: Engineers Use Air Voids to Create Cooling Paint
www.engineering.com ^ | October 08, 2018 | Emily Pollock

Posted on 11/08/2018 12:59:53 PM PST by Red Badger

A board coated in the new polymer paint stays significantly cooler than its surroundings, even in direct sunlight, as seen under ultraviolet lights. (Image courtesy of Columbia University.)

___________________________________________________________________

A team of engineers from Columbia University has created a polymer coating that uses nano-to-microscale air voids to reflect sunlight and cool down buildings.

Passive daytime radiative cooling (PDRC) is a phenomenon where a surface spontaneously cools by reflecting sunlight and radiating heat to a cooler atmosphere. PDRC works best if a surface has high solar reflectance—meaning that most of the sun’s radiation is reflected away—and a high thermal emittance—meaning that it very easily radiates heat into the atmosphere.

To find a coating with better PDRC than white paint (the current industry standard), the researchers wanted to develop a polymer coating with air voids (pockets of air between coated aggregate particles) inside of it. These micro-and-nano-scale “bubbles” scatter and reflect sunlight to avoid solar heating, and also mean that the polymer loses intrinsic heat easily. To create this coating, the researchers started by preparing a precursor solution of polymer and water in acetone, then applied a film of the solution onto a surface and left it to dry. When the acetone evaporated, the polymer phase-separated from the water, making micro and nano droplets of water. When that water evaporated, the researchers were left with “bubbles” in the polymer.

Previous research had shown that polymers were capable of PDRC, but there was no consensus on how to get transparent polymers to reflect sunlight, and there was no easy method of applying polymers to a surface. The research team solved the second problem by creating paint with its polymer in it instead of using a traditional white pigment. By making this substitution, the researchers were able to create a “white paint” that doesn’t absorb UV radiation. "This simple but fundamental modification yields exceptional [solar reflectance] and [thermal emittance] that equal or surpass those of state-of-the-art PDRC designs, but with a convenience that is almost paint-like," said doctoral student Jyotirmoy Mandal, the study’s lead author.

The paint worked in multiple hot climates, from the tropical to the desert, and the researchers were able to dye it different colors without losing its passive cooling abilities. The team is currently working on how to make its paint usable on a wide scale, and is in talks with larger industrial players. The researchers hope that their paint could become a useful tool in the battle against global climate change.

"Now is a critical time to develop promising solutions for sustainable humanity," said Yuan Yang, assistant professor of material sciences and engineering, and also one of the study’s authors. "This year, we witnessed heat waves and record-breaking temperatures in North America, Europe, Asia, and Australia. It is essential that we find solutions to this climate challenge, and we are very excited to be working on this new technology that addresses it."

Read the original article, published in the Science journal:

Hierarchically porous polymer coatings for highly efficient passive daytime radiative cooling

http://science.sciencemag.org/content/early/2018/09/26/science.aat9513

Abstract

Passive daytime radiative cooling (PDRC) involves spontaneously cooling a surface by reflecting sunlight and radiating heat to the cold outer space. Current PDRC designs are promising alternatives to electrical cooling, but are either inefficient or have limited applicability. We present a simple, inexpensive and scalable phase-inversion-based method for fabricating hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene) (P(VdF-HFP)HP) coatings with excellent PDRC capability. High, substrate-independent hemispherical solar reflectances (0.96 ± 0.03) and long-wave infrared (LWIR) emittances (0.97 ± 0.02) allow for sub-ambient temperature drops of ~6°C and cooling powers of ~96 W m−2 under solar intensities of 890 and 750 W m−2 respectively. The performance equals or surpasses those of state-of-the-art PDRC designs, while the technique offers a paint-like simplicity.


TOPICS: Business/Economy; Education; Health/Medicine; Science
KEYWORDS: coating; energy; paint; reflective
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Cool!..............LITERALLY!................
1 posted on 11/08/2018 12:59:53 PM PST by Red Badger
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To: Red Badger
A board coated in the new polymer paint stays significantly cooler than its surroundings, even in direct sunlight, as seen under ultraviolet infrared lights. (Image courtesy of Columbia University.)

There, fixed it. Dumb reporters.

2 posted on 11/08/2018 1:05:55 PM PST by Yo-Yo (Is the /sarc tag really necessary?)
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To: Red Badger

LOL - you beat me to it!


3 posted on 11/08/2018 1:08:42 PM PST by taxcontrol
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To: Yo-Yo

Thank you. Sometimes, I want to strangle reporters.


4 posted on 11/08/2018 1:15:02 PM PST by NorthMountain (... the right of the peopIe to keep and bear arms shall not be infringed)
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To: Yo-Yo
the researchers were able to create a “white paint” that doesn’t absorb UV radiation.
5 posted on 11/08/2018 1:15:12 PM PST by Red Badger (FNo-platform us all you want. Ban us all you want. Smear us all you want. You canÂ’t stop an idea...)
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To: Red Badger

I wonder if durability is effected?


6 posted on 11/08/2018 1:16:09 PM PST by Truth29
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To: Red Badger
but there was no consensus on how to get transparent polymers to reflect sunlight

Beer is transmissive.

Beer Foam is reflective.

7 posted on 11/08/2018 1:19:18 PM PST by NorthMountain (... the right of the peopIe to keep and bear arms shall not be infringed)
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To: Truth29

I don’t know, it’s full of holes...................


8 posted on 11/08/2018 1:19:20 PM PST by Red Badger (FNo-platform us all you want. Ban us all you want. Smear us all you want. You canÂ’t stop an idea...)
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To: NorthMountain

I make beer disappear.

What is your superpower?.....................


9 posted on 11/08/2018 1:20:25 PM PST by Red Badger (FNo-platform us all you want. Ban us all you want. Smear us all you want. You canÂ’t stop an idea...)
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To: NorthMountain

Beer is good!


10 posted on 11/08/2018 1:20:32 PM PST by Reily
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To: Red Badger

What’s really impressive, here, is that they have achieved high reflectivity in the visible wavelengths AND high emissivity in the thermal wavelengths. Clever to achieve it with foam.


11 posted on 11/08/2018 1:20:58 PM PST by NorthMountain (... the right of the peopIe to keep and bear arms shall not be infringed)
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To: Reily

Beer is good. There’s also a lot of physics to learn from a glass of beer.


12 posted on 11/08/2018 1:21:49 PM PST by NorthMountain (... the right of the peopIe to keep and bear arms shall not be infringed)
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To: NorthMountain

Dammit...now Im thirsty...too thirsty.


13 posted on 11/08/2018 1:22:41 PM PST by gnarledmaw (Hive minded liberals worship leaders, sovereign conservatives elect servants.)
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To: Red Badger
What is your superpower?.....................

I make beer.

14 posted on 11/08/2018 1:22:45 PM PST by NorthMountain (... the right of the peopIe to keep and bear arms shall not be infringed)
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To: Red Badger
"Now is a critical time to develop promising solutions for sustainable humanity,"

Anyone else find themselves interested in a product or service, and then see this sustainability crap and find it not so interesting anymore?

I'm getting to the point where I don't care how much I want/need something, I'm not going to support this silliness anymore.
15 posted on 11/08/2018 1:27:03 PM PST by chrisser
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To: chrisser

Ferengi Rules of Acquisition #13:

Anything worth doing is worth doing for money.


16 posted on 11/08/2018 1:38:28 PM PST by Red Badger (FNo-platform us all you want. Ban us all you want. Smear us all you want. You canÂ’t stop an idea...)
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To: Red Badger

I need some of that for painting my beach house in the South Pacific... after I can afford to buy a beach house in the South Pacific.


17 posted on 11/08/2018 1:40:51 PM PST by Two Kids' Dad (((( Sessions couldn't find his own ass if Al Franken was grabbing it at the time ))))
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To: Red Badger
the researchers were able to create a “white paint” that doesn’t absorb UV radiation.

Here's the original YouTube video where that image with the ultraviolet caption originated from. In the video the image is clearly from an infrared camera, with a temperature scale on the right side showing the correlation between the false colors and temperature. You can watch the entire video, but I have cued it up to the relevant shot here:

https://youtu.be/8lTdZ-U0Qm8?t=107

The underlying abstract paper does mention UV reflectance as an advantage of the coating not breaking down after prolonged exposure to sunlight.

But the captioned image is NOT of ultraviolet light. It is of near infrared.

18 posted on 11/08/2018 1:47:48 PM PST by Yo-Yo (Is the /sarc tag really necessary?)
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To: Yo-Yo

It’s racist paint.
If it were any other color than ‘white’....................


19 posted on 11/08/2018 1:55:09 PM PST by Red Badger (FNo-platform us all you want. Ban us all you want. Smear us all you want. You canÂ’t stop an idea...)
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To: Red Badger

Does Null and Void know about this?


20 posted on 11/08/2018 1:57:30 PM PST by Fungi
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